{"id":"W6903144640","doi":"10.1021/ja201237j.s001","title":"Asymmetric Rh(II)-Catalyzed Cyclopropanation of Alkenes with Diacceptor Diazo Compounds: &lt;i&gt;p&lt;/i&gt;-Methoxyphenyl Ketone as a General Stereoselectivity Controlling Group","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Cyclopropanation; Stereoselectivity; Diazo; Enantiopure drug; Cyclopropane; Moiety; Lewis acids and bases; Carbene","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002080037,0.0005851961,0.0008281557,0.0004006873,0.0003003513,0.00009421782,0.0005371025,0.0003427759,0.02401474],"category_scores_gemma":[0.001367487,0.0004450797,0.0002831686,0.0008492623,0.00004493938,0.0006096843,0.0002481036,0.0002727261,0.0003784802],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004980963,"about_ca_system_score_gemma":0.0002110265,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003617604,"about_ca_topic_score_gemma":0.000128405,"domain_scores_codex":[0.9966149,0.0001234776,0.0006886476,0.0009093016,0.0009761377,0.0006875152],"domain_scores_gemma":[0.9966884,0.0007127749,0.0008579847,0.0008030347,0.0006617605,0.000276004],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003905281,0.0002668329,0.0001454487,0.0004510526,0.0002168749,0.00001804036,0.0001357833,0.0000112605,0.9607742,0.000173678,0.001788049,0.0356282],"study_design_scores_gemma":[0.005162568,0.0002607799,0.001793638,0.00163349,0.0001372772,0.00007762787,0.00004879307,0.0003170185,0.9407932,0.0001579398,0.04870044,0.0009172507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9126444,0.002566271,0.001023424,0.0001432399,0.0002592122,0.00127275,0.06327409,0.0008430629,0.01797354],"genre_scores_gemma":[0.9800467,0.00005418673,0.001640031,0.00003175879,0.0005017518,0.0005573557,0.01579925,0.0001447386,0.001224227],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0674023,"threshold_uncertainty_score":0.9998001,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01491242747376655,"score_gpt":0.2344397374852965,"score_spread":0.2195273100115299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}