{"id":"W6903156567","doi":"10.1021/ol051381u.s001","title":"Formal Intramolecular Photoredox\\nChemistry of Meta-Substituted\\nBenzophenones","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Radical Photochemical Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Intramolecular force; Photodissociation; Moiety; Benzene; Photoredox catalysis; Aqueous solution; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001729697,0.000410202,0.0001502504,0.00009777795,0.0001426367,0.0002189538,0.0003207212,0.0001506764,0.002219069],"category_scores_gemma":[0.0002349514,0.0001195988,0.0001479061,0.0001312121,0.0002660364,0.0002092834,0.000254717,0.0005490829,0.0003669297],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003641428,"about_ca_system_score_gemma":0.0001900214,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001183751,"about_ca_topic_score_gemma":0.001841584,"domain_scores_codex":[0.9998844,0.00001590467,0.00000520616,0.000025123,0.00002136507,0.00004805125],"domain_scores_gemma":[0.9999124,0.00002489282,0.00001882901,0.00002066429,0.000009491381,0.00001372615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004711977,0.00001271629,0.00006344881,0.00005234924,0.000005455561,0.00006913917,0.00005145303,0.0001168371,0.99694,0.0008057309,0.00007131136,0.001764511],"study_design_scores_gemma":[0.000005632956,0.00007627341,0.0004638972,0.000002204219,0.000002703552,0.00004173603,0.00000940462,0.0002293856,0.9983628,0.00003276223,0.0007704856,0.000002632041],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916863,0.0004314616,0.003020258,0.00007002567,0.00003202892,0.00002040022,0.00008687088,0.00009145036,0.004561164],"genre_scores_gemma":[0.9963373,0.0002990151,0.001109742,0.00001767511,0.000005264564,0.00001092825,0.00007078657,0.00001563904,0.002133701],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002219069,"threshold_uncertainty_score":0.00742358,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04058302655516706,"score_gpt":0.2473502234330799,"score_spread":0.2067671968779129,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}