{"id":"W6903170012","doi":"10.1021/ic100383p.s001","title":"Syntheses and Multi-NMR Study of <i>fac</i>- and <i>mer</i>-OsO<sub>3</sub>F<sub>2</sub>(NCCH<sub>3</sub>) and the X-ray Crystal Structure (<i>n</i> = 2) and Raman Spectrum (<i>n</i> = 0) of <i>fac</i>-OsO<sub>3</sub>F<sub>2</sub>(NCCH<sub>3</sub>)·<i>n</i>CH<sub>3</sub>CN","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Molecule; Raman spectroscopy; Crystal structure; Adduct; Solvent; NMR spectra database; Atom (system on chip); Resonance (particle physics); Singlet state; Crystal (programming language)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"category_scores_codex":[0.02697041,0.05126019,0.04883588,0.0233637,0.02626296,0.0178198,0.04419504,0.03565157,0.02282916],"category_scores_gemma":[0.02543459,0.0511556,0.02342931,0.03286812,0.02707326,0.02311767,0.03454795,0.0298846,0.01223532],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.01961748,"about_ca_system_score_gemma":0.01861726,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000437246,"about_ca_topic_score_gemma":0.02379442,"domain_scores_codex":[0.8158544,0.01771977,0.04241513,0.04370328,0.03700457,0.04330283],"domain_scores_gemma":[0.8523245,0.02417332,0.03511225,0.04091096,0.02081001,0.02666898],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.01514808,0.01682708,0.0008935691,0.01246187,0.02113894,0.008128045,0.009769052,0.002897526,0.6710159,0.01280098,0.212386,0.01653297],"study_design_scores_gemma":[0.07586031,0.01235292,0.0102963,0.02651816,0.02348986,0.01107681,0.002001957,0.01367465,0.2628295,0.005033292,0.5038615,0.05300467],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6305778,0.1485018,0.001257513,0.005866433,0.01902656,0.03860702,0.1143219,0.01485806,0.02698294],"genre_scores_gemma":[0.8090211,0.0748525,0.00377832,0.003906404,0.0201686,0.01420488,0.03964395,0.01686248,0.01756182],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4081864,"threshold_uncertainty_score":0.9940188,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01272951914085295,"score_gpt":0.2160786793074849,"score_spread":0.203349160166632,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}