{"id":"W6903177346","doi":"10.1021/ja036808b.s001","title":"Photohydration and Photosolvolysis of Biphenyl Alkenes and\\nAlcohols via Biphenyl Quinone Methide-type Intermediates\\nand Diarylmethyl Carbocations","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Flash photolysis; Carbocation; Biphenyl; Alkene; Photodissociation; Quenching (fluorescence); Aqueous solution; Intramolecular force; Singlet oxygen; Solvent","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009287001,0.0002419143,0.00007066925,0.0001106234,0.0001031456,0.0001124841,0.0001700662,0.0001512423,0.001328539],"category_scores_gemma":[0.00009002918,0.00008033737,0.0001207956,0.00009306141,0.0001496625,0.0001698518,0.000154122,0.0002390866,0.0002143379],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003214911,"about_ca_system_score_gemma":0.0001332155,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007305465,"about_ca_topic_score_gemma":0.0008664936,"domain_scores_codex":[0.9999419,0.000006662531,0.000002254416,0.00001078772,0.00001405715,0.00002422595],"domain_scores_gemma":[0.999958,0.000006910587,0.00001347461,0.000005720845,0.00000784425,0.000007938291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005303582,0.000009415404,0.00009065052,0.00003061733,0.000001959325,0.00004356197,0.00002422915,0.0001557664,0.9977819,0.0002985982,0.00003481908,0.001475424],"study_design_scores_gemma":[0.000004057993,0.00007564708,0.0004821984,0.000001106392,0.000001740828,0.00002943994,0.000009594653,0.0005145836,0.9983626,0.00003028049,0.0004867881,0.000001950937],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.993443,0.0004299073,0.003347189,0.00004246716,0.00001044846,0.0000140266,0.00009201707,0.00005768444,0.002563277],"genre_scores_gemma":[0.9977388,0.0001980676,0.0008761347,0.0000118312,0.000002024887,0.000005716833,0.00008016604,0.000007395888,0.001079831],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001328539,"threshold_uncertainty_score":0.004444361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01908176850658108,"score_gpt":0.2448336587112941,"score_spread":0.225751890204713,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}