{"id":"W6903211261","doi":"10.1021/jo401488y.s001","title":"Studies toward the Generation of Functionalized Quaternary\\nCarbon Centers Relying on Wittig and Wittig–Still Allylic Ether\\nAnionic Transpositions","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Allylic rearrangement; Ring (chemistry); Wittig reaction; Product (mathematics); Ether","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004038433,0.0001419474,0.0001505287,0.00003001094,0.0001643516,0.00002054683,0.0001067592,0.00007267298,0.007776756],"category_scores_gemma":[0.0001034227,0.0000803429,0.00009117132,0.0000619205,0.00003350621,0.0001024138,0.00002859598,0.0001098277,0.00003960489],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006751958,"about_ca_system_score_gemma":0.00003308071,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002070878,"about_ca_topic_score_gemma":0.00002092372,"domain_scores_codex":[0.999221,0.00002670888,0.0002069514,0.000220839,0.0001796474,0.0001448137],"domain_scores_gemma":[0.9993002,0.0002212711,0.000120175,0.0002142488,0.0000994377,0.00004465886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002967367,0.0002888901,0.0005783656,0.0005019188,0.0009408821,0.00001372138,0.004071677,0.0001249234,0.9318626,0.00097821,0.05034005,0.010002],"study_design_scores_gemma":[0.006943861,0.0005507351,0.008518931,0.01954426,0.0004656249,0.0001465912,0.002702925,0.001907396,0.5834109,0.001842666,0.3724324,0.001533688],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8944333,0.00952324,0.00005970545,0.01207594,0.0005892602,0.00060087,0.07264264,0.0003403995,0.009734668],"genre_scores_gemma":[0.9960929,0.0002991213,0.00002140434,0.0001079175,0.0001642768,0.0001351612,0.002403537,0.00001971644,0.0007559964],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3484517,"threshold_uncertainty_score":0.9931303,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1247816847978516,"score_gpt":0.2900080427031262,"score_spread":0.1652263579052746,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}