{"id":"W6903211261","doi":"10.1021/jo401488y.s001","title":"Studies toward the Generation of Functionalized Quaternary\\nCarbon Centers Relying on Wittig and Wittig–Still Allylic Ether\\nAnionic Transpositions","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Allylic rearrangement; Ring (chemistry); Wittig reaction; Product (mathematics); Ether","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004489693,0.0005200947,0.0002258305,0.0003478227,0.0002400912,0.0003070863,0.0005966512,0.0003302085,0.004218691],"category_scores_gemma":[0.0003841477,0.0001583615,0.0002536164,0.000511624,0.000445328,0.0008457627,0.0004272124,0.0007110169,0.0008464028],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000360902,"about_ca_system_score_gemma":0.0003294692,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004149384,"about_ca_topic_score_gemma":0.0009036844,"domain_scores_codex":[0.9998581,0.00002155145,0.0000110248,0.0000283453,0.00003231362,0.00004866509],"domain_scores_gemma":[0.9999144,0.00002154163,0.0000196436,0.00001821809,0.0000159888,0.00001024108],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002946962,0.000299664,0.0004053797,0.001580083,0.00008140389,0.0009289106,0.0006348515,0.003068731,0.8929495,0.0412957,0.001512577,0.05694843],"study_design_scores_gemma":[0.00002653388,0.0007619176,0.0003559213,0.00002294004,0.00003384542,0.0003987538,0.00006186013,0.001220637,0.9748195,0.0011084,0.02116627,0.00002352601],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8955675,0.008416022,0.03897383,0.0005130351,0.0001939211,0.0002355872,0.0005131929,0.0002932668,0.05529379],"genre_scores_gemma":[0.9726275,0.008054618,0.009799301,0.0001122943,0.0000366695,0.00005493945,0.0003970895,0.00005438646,0.008863118],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004218691,"threshold_uncertainty_score":0.01411295,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1247816847978516,"score_gpt":0.2900080427031262,"score_spread":0.1652263579052746,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}