{"id":"W6903225000","doi":"10.1021/jo201673w.s001","title":"Enantioselective de Novo\\nSynthesis of 4-Deoxy-d-hexopyranoses via Hetero-Diels–Alder\\nCycloadditions:\\nTotal Synthesis of Ezoaminuroic Acid and Neosidomycin","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"","keywords":"Enantioselective synthesis; Optically active; Catalysis; Dihydropyran; Chemical synthesis; Organic synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001704504,0.0004281882,0.000253423,0.0001998316,0.0001388997,0.000226755,0.0002649801,0.0001988338,0.001356029],"category_scores_gemma":[0.0001203742,0.000138625,0.000211826,0.000294152,0.0001290907,0.0002701119,0.0003494256,0.0005242029,0.0008384211],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003123263,"about_ca_system_score_gemma":0.0005096819,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007067911,"about_ca_topic_score_gemma":0.001678326,"domain_scores_codex":[0.9998891,0.00001110996,0.00001187993,0.00002168015,0.00002267965,0.00004346417],"domain_scores_gemma":[0.9999472,0.000005333281,0.00001134078,0.00001116762,0.000007789285,0.00001720472],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001125568,0.0001224185,0.0002206072,0.0001550846,0.00001680598,0.0003345962,0.0001235207,0.001288947,0.9778816,0.002895839,0.0002963325,0.0165516],"study_design_scores_gemma":[0.00001981524,0.0001871578,0.0004903826,0.000006745925,0.000009356514,0.0001241188,0.00002794504,0.00111522,0.9895914,0.0001966264,0.008219184,0.00001208376],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9219308,0.0031287,0.04753695,0.0001741158,0.000214951,0.0003990026,0.001833114,0.000415411,0.02436694],"genre_scores_gemma":[0.9553053,0.003022346,0.03222763,0.00007182244,0.00001727405,0.0001396165,0.001058233,0.00006938741,0.008088266],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001356029,"threshold_uncertainty_score":0.00453639,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01221873827585514,"score_gpt":0.2099719560803828,"score_spread":0.1977532178045276,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}