{"id":"W6903259964","doi":"10.1021/ol402617a.s001","title":"Nicholas Reactions in the Synthesis of Dicobalt Dibenzocyclooctyne Complexes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Intramolecular force; Catalysis; Reductive elimination; Formal synthesis; Reaction conditions","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00005127932,0.0001059717,0.0001462239,0.00004862429,0.00005978713,0.00001663449,0.0003381011,0.00007481717,0.1299476],"category_scores_gemma":[0.002577028,0.00006409284,0.000096698,0.0001655182,0.0000202545,0.0001285663,0.00006365659,0.0001295747,0.0009690106],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008519216,"about_ca_system_score_gemma":0.0000450878,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000700188,"about_ca_topic_score_gemma":0.0001054802,"domain_scores_codex":[0.9991878,0.00001747736,0.0002452158,0.0001716202,0.0002004165,0.0001775101],"domain_scores_gemma":[0.9977014,0.00154184,0.0001299394,0.0005376927,0.00005133703,0.00003779352],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00004812465,0.0008376125,0.002224708,0.0009026828,0.0001821186,0.00004380365,0.0005178428,0.000007686422,0.3887599,0.0009351548,0.5530137,0.05252666],"study_design_scores_gemma":[0.0004672685,0.00001009278,0.01668189,0.004317776,0.00004429264,0.00009102569,0.0005814521,0.00001618021,0.2757628,0.0004061887,0.7013144,0.0003066752],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.08367296,0.0004038777,0.000004198393,0.002562086,0.00007233502,0.0003094095,0.585082,0.0002395134,0.3276536],"genre_scores_gemma":[0.9951711,0.0000110826,0.00001188863,0.00002454404,0.00008657458,0.0002162188,0.003350559,0.00001646954,0.001111612],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.9114981,"threshold_uncertainty_score":0.9998088,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03954805973441984,"score_gpt":0.2699285650229828,"score_spread":0.230380505288563,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}