{"id":"W6903345404","doi":"10.1021/jo2008093.s001","title":"A Microwave-Assisted Synthesis of (&lt;i&gt;S&lt;/i&gt;)-&lt;i&gt;N&lt;/i&gt;-Protected Homoserine γ-Lactones from l-Aspartic Acid","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Microwave-Assisted Synthesis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Homoserine; Microwave irradiation; Yield (engineering); Methanol; Lactic acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0002376159,0.001255249,0.001609622,0.0003029698,0.0005578629,0.0002257002,0.001922293,0.001022271,0.2101512],"category_scores_gemma":[0.003104232,0.001077232,0.0009052346,0.0009156705,0.0002049311,0.0004207451,0.0006867556,0.0004533873,0.005225253],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003865199,"about_ca_system_score_gemma":0.0003972803,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002290567,"about_ca_topic_score_gemma":0.000558056,"domain_scores_codex":[0.9935913,0.0002347685,0.001841301,0.001867665,0.0009797456,0.001485233],"domain_scores_gemma":[0.9923874,0.001707014,0.00136862,0.003101373,0.000746271,0.0006892856],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001781896,0.0006204205,0.00003133761,0.0006064835,0.0004673506,0.00004011144,0.000134948,0.000001387651,0.89083,0.0001601624,0.07974052,0.02718903],"study_design_scores_gemma":[0.001099621,0.00005089892,0.00560008,0.004209604,0.0002828215,0.00003396223,0.00002869496,0.00008558533,0.7334046,0.0001104539,0.2539754,0.001118311],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.5383152,0.006307947,0.0001240448,0.001313975,0.0001865836,0.001617434,0.4214104,0.001419408,0.02930503],"genre_scores_gemma":[0.973009,0.0001709328,0.00163512,0.0001020321,0.0004835881,0.002739549,0.01653802,0.0003394473,0.00498224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4346938,"threshold_uncertainty_score":0.9991678,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02596926525407455,"score_gpt":0.2319305633169635,"score_spread":0.2059612980628889,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}