{"id":"W6921415166","doi":"10.7907/h8ap-g249","title":"Copper Carbazolides in Photoinduced C–N Couplings","year":2018,"lang":"en","type":"article","venue":"CaltechTHESIS (California Institute of Technology)","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; California Institute of Technology","keywords":"Copper; Denticity; Alkyl; Ligand (biochemistry); Carbazole; Nucleophile; Reactive intermediate; Photoredox catalysis; Catalysis; Transition metal","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004059454,0.0002981709,0.0005246009,0.0007131982,0.0001170361,0.00001716643,0.0006225437,0.0006529466,0.001093561],"category_scores_gemma":[0.001628691,0.0003036036,0.0001257083,0.001327898,0.001258779,0.0001293738,0.0002181069,0.0003898338,0.0002559081],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002613591,"about_ca_system_score_gemma":0.0002127641,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00009852472,"about_ca_topic_score_gemma":0.00008802252,"domain_scores_codex":[0.9979356,0.000008880011,0.0007520707,0.0005579575,0.0003185868,0.0004269],"domain_scores_gemma":[0.9983717,0.00007733098,0.00028521,0.0008815144,0.0002961742,0.0000881391],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002116809,0.0002780221,0.02551014,0.0002473282,0.0001047377,0.00003336227,0.00006259865,0.00007763467,0.9321117,0.01284286,0.00168551,0.02683445],"study_design_scores_gemma":[0.0007463017,0.00003164963,0.000224752,0.0001817784,0.00004081821,0.00004102986,0.00009224736,0.0007307805,0.8122601,0.003885699,0.1814637,0.0003011214],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9832526,0.0001877543,0.0024948,0.0008736738,0.0003594633,0.0001884386,0.0001115855,0.0005428875,0.01198883],"genre_scores_gemma":[0.9800779,0.00004787399,0.01901496,0.0001346686,0.0001625654,0.00009824603,0.00004163049,0.00005178626,0.0003703369],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1797782,"threshold_uncertainty_score":0.9999416,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02307179197764414,"score_gpt":0.2773698643363131,"score_spread":0.2542980723586689,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}