{"id":"W6921766357","doi":"10.1021/jo1016713.s001","title":"Synthesis of Substituted Indole from 2-Aminobenzaldehyde\\nthrough [1,2]-Aryl Shift","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Merck Canada Inc. (Canada)","funders":"","keywords":"Indole test; Functional group; Anthranilic acid; Simple (philosophy); Group (periodic table)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00001979374,0.000213201,0.0002822405,0.00004970935,0.00005401023,0.00001801878,0.0003616534,0.0002374396,0.5091578],"category_scores_gemma":[0.001180407,0.0001663331,0.0001360454,0.0001112058,0.00001537224,0.0002029993,0.0001295981,0.0001205627,0.002884144],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001094629,"about_ca_system_score_gemma":0.0000869982,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00008169069,"about_ca_topic_score_gemma":0.0000323614,"domain_scores_codex":[0.9987246,0.0000117503,0.0003119862,0.0003753289,0.0003104278,0.0002659319],"domain_scores_gemma":[0.9984767,0.0005250745,0.0002238182,0.0005640285,0.0001039328,0.0001063888],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007590934,0.0001379007,0.0003983449,0.0005602086,0.0001199005,0.00005187612,0.0003432777,0.000002548851,0.9232231,0.00009095718,0.02193372,0.05306224],"study_design_scores_gemma":[0.0003687643,0.000005625149,0.001036342,0.002402224,0.00002293941,0.00000358736,0.00009175033,0.000005198921,0.9459336,0.0001741646,0.04972488,0.0002309677],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.3658624,0.0005481381,0.00002164337,0.000166995,0.0001494993,0.0001930325,0.6090334,0.0005088735,0.02351599],"genre_scores_gemma":[0.9856927,0.000009661357,0.0001729112,0.00002037778,0.0002323666,0.0001557144,0.01345453,0.00004780668,0.0002138935],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6198303,"threshold_uncertainty_score":0.9978922,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02769636450785411,"score_gpt":0.2351374754558461,"score_spread":0.207441110947992,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}