{"id":"W6921783107","doi":"10.1021/jo3014098.s001","title":"From Chiral <i>ortho</i>-Benzoquinone Monoketals to Nonracemic Indolinocodeines through Diels–Alder and Cope Reactions","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Traditional and Medicinal Uses of Annonaceae","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Yield (engineering); Ring (chemistry); Palladium; Catechol; Oxygen; Catalysis; Terminal (telecommunication)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002144068,0.0005029035,0.0001588687,0.0003481556,0.0001892578,0.0002064107,0.0002956658,0.0001656858,0.004300574],"category_scores_gemma":[0.0001620814,0.0001785607,0.000200409,0.0002858102,0.0002521745,0.0004269952,0.0005627383,0.0005381949,0.002605022],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003107456,"about_ca_system_score_gemma":0.0003621322,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000263782,"about_ca_topic_score_gemma":0.001034212,"domain_scores_codex":[0.999871,0.00001658053,0.000009106614,0.00003108994,0.00002932125,0.00004289496],"domain_scores_gemma":[0.9999427,0.000004421089,0.00001082689,0.000009652981,0.000009865633,0.00002251503],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001524579,0.0001584644,0.0002624656,0.000645304,0.0000266643,0.0006403564,0.0003841274,0.0009090656,0.9506611,0.01184986,0.001882423,0.03242777],"study_design_scores_gemma":[0.00005802708,0.0006994667,0.00120421,0.00003910949,0.00002085513,0.0005827182,0.00007432301,0.001260835,0.9114623,0.001541923,0.08300985,0.00004638152],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7867047,0.009401354,0.11368,0.001015594,0.0006529829,0.0008668688,0.001911307,0.001056987,0.08471029],"genre_scores_gemma":[0.942404,0.005505534,0.02304603,0.0002156371,0.0000553981,0.0002024862,0.0009976981,0.0001248757,0.02744834],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004300574,"threshold_uncertainty_score":0.01438683,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02447113174806691,"score_gpt":0.2607419142801187,"score_spread":0.2362707825320517,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}