{"id":"W6921821555","doi":"10.1021/acs.joc.5b00164.s001","title":"Regioselective Hydration\\nof Terminal Alkynes Catalyzed\\nby a Neutral Gold(I) Complex [(IPr)AuCl] and One-Pot Synthesis of\\nOptically Active Secondary Alcohols from Terminal Alkynes by the Combination\\nof [(IPr)AuCl] and Cp*RhCl[(<i>R</i>,<i>R</i>)‑TsDPEN]","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"","keywords":"Terminal (telecommunication); Cationic polymerization; Catalysis; Yield (engineering); Regioselectivity; Optically active","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.0003514183,0.001494482,0.001735384,0.0004159377,0.0009887797,0.0005106023,0.001493945,0.0009115615,0.02035789],"category_scores_gemma":[0.002857842,0.001258535,0.0005710394,0.0006942471,0.0009699566,0.001811838,0.0008840301,0.0009100247,0.0003975738],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007213182,"about_ca_system_score_gemma":0.0009913285,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000115865,"about_ca_topic_score_gemma":0.0008578841,"domain_scores_codex":[0.993001,0.0003073812,0.001691874,0.00220898,0.00130975,0.001480991],"domain_scores_gemma":[0.9894705,0.005297281,0.001475864,0.001887744,0.001053348,0.0008152113],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005993861,0.0009692193,0.0001021846,0.0006124437,0.001201675,0.0001492604,0.001498605,0.000004428145,0.8421755,0.0007634957,0.1200987,0.03182504],"study_design_scores_gemma":[0.009636203,0.0006833552,0.06405425,0.007507772,0.002651252,0.002050734,0.0009169768,0.001396303,0.6500032,0.002986327,0.2529801,0.005133539],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6469414,0.002554176,0.00004646034,0.003442767,0.0002307867,0.002143411,0.3114386,0.0005900336,0.03261231],"genre_scores_gemma":[0.9673975,0.0001917944,0.0003097634,0.0002292416,0.0005889887,0.001179627,0.0249432,0.0002745854,0.004885327],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3204561,"threshold_uncertainty_score":0.9997804,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02204058470881251,"score_gpt":0.241401182171198,"score_spread":0.2193605974623855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}