{"id":"W6921821555","doi":"10.1021/acs.joc.5b00164.s001","title":"Regioselective Hydration\\nof Terminal Alkynes Catalyzed\\nby a Neutral Gold(I) Complex [(IPr)AuCl] and One-Pot Synthesis of\\nOptically Active Secondary Alcohols from Terminal Alkynes by the Combination\\nof [(IPr)AuCl] and Cp*RhCl[(<i>R</i>,<i>R</i>)‑TsDPEN]","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"","keywords":"Terminal (telecommunication); Cationic polymerization; Catalysis; Yield (engineering); Regioselectivity; Optically active","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001118343,0.0005522243,0.0002375218,0.000106943,0.0001475137,0.0001443695,0.0003477306,0.0002007433,0.001134318],"category_scores_gemma":[0.0001084578,0.0001733933,0.0002188716,0.0001316964,0.0001972085,0.0003011519,0.00037682,0.0004705711,0.0003820529],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003370675,"about_ca_system_score_gemma":0.0003300772,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001646468,"about_ca_topic_score_gemma":0.003600967,"domain_scores_codex":[0.9998813,0.00001025409,0.000009739882,0.00003166095,0.0000220827,0.00004499009],"domain_scores_gemma":[0.999959,0.000003642565,0.00001220424,0.000007972651,0.00000692285,0.00001032105],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008427102,0.00003210982,0.0001083794,0.0001392918,0.00001073755,0.0001406231,0.00008368208,0.0002476216,0.9947374,0.0005177799,0.0001982347,0.003699812],"study_design_scores_gemma":[0.000009643621,0.00007874562,0.0002945672,0.000002948794,0.000006015276,0.00008218164,0.00001205705,0.0004092407,0.997485,0.00002514958,0.001588213,0.000006176015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9743171,0.0009488499,0.01120174,0.0001296378,0.00007635149,0.0001528381,0.0003671931,0.000294374,0.01251197],"genre_scores_gemma":[0.9932417,0.000565096,0.002475449,0.0000227837,0.000006091337,0.00003198409,0.0002109704,0.00002912462,0.00341691],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001646468,"threshold_uncertainty_score":0.003794611,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02204058470881251,"score_gpt":0.241401182171198,"score_spread":0.2193605974623855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}