{"id":"W6921900437","doi":"10.1021/jo3024973.s001","title":"Synthesis of 7‑Oxabicyclo[2.2.1]heptanes and\\n8‑Oxabicyclo[3.2.1]octanes from C‑Glycosides via an\\nIntramolecular Cyclization","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Stereoselectivity; Anomer; Epimer; Intramolecular force; Nucleophilic substitution; Substitution (logic)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009406378,0.0003506279,0.0001784409,0.0002477768,0.0002101889,0.0002094631,0.000192325,0.0001304958,0.003777446],"category_scores_gemma":[0.00006567135,0.0001705897,0.0001585091,0.0002082771,0.000100942,0.0002227368,0.0002475239,0.000364217,0.001314053],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001943465,"about_ca_system_score_gemma":0.0005122615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004733243,"about_ca_topic_score_gemma":0.001546523,"domain_scores_codex":[0.9999281,0.000007920887,0.000005807398,0.00001179174,0.00001683152,0.00002955589],"domain_scores_gemma":[0.999961,0.000002216262,0.000005168664,0.000003671604,0.000009280183,0.00001863759],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001696267,0.00009896012,0.0002162523,0.0002811958,0.00001276821,0.0003836072,0.000126635,0.0006103545,0.9687242,0.003472966,0.0006523198,0.02525103],"study_design_scores_gemma":[0.00008551271,0.0008843087,0.001842307,0.00003802936,0.00001836874,0.0004488419,0.0000922895,0.0008079254,0.9367102,0.0006650363,0.05836716,0.0000400881],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9072768,0.005281263,0.02670523,0.0002266525,0.0006197504,0.0005218717,0.002083874,0.0002715891,0.05701292],"genre_scores_gemma":[0.9277939,0.006266247,0.02939215,0.0002010869,0.000071378,0.0003101122,0.001949547,0.00008434537,0.03393115],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003777446,"threshold_uncertainty_score":0.01263678,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01720836448302114,"score_gpt":0.2507065185179982,"score_spread":0.2334981540349771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}