{"id":"W6921916429","doi":"10.1021/ol070994z.s001","title":"Enantioselective Total Synthesis of\\nCyathin A&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;†&lt;/sup&gt;","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Plant-derived Lignans Synthesis and Bioactivity","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Enantioselective synthesis; Total synthesis; Catalysis; Stereoisomerism; Yield (engineering)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001104342,0.0005551846,0.000316583,0.0002970967,0.0002704781,0.0002352356,0.0003261424,0.000177759,0.004945965],"category_scores_gemma":[0.00008185257,0.0001726264,0.0002774431,0.000360075,0.0001601489,0.000330256,0.0004379178,0.0006624783,0.001936282],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003728061,"about_ca_system_score_gemma":0.0005334658,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001085287,"about_ca_topic_score_gemma":0.001231517,"domain_scores_codex":[0.999916,0.000005370695,0.000005001186,0.00002556165,0.00001607716,0.00003194746],"domain_scores_gemma":[0.9999529,0.000004105996,0.000006893885,0.000011936,0.000009067011,0.00001508399],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001013778,0.00005881469,0.0001547812,0.0001960193,0.00002522987,0.0002942673,0.00009690895,0.0007477874,0.9739798,0.003236967,0.0007382987,0.02036974],"study_design_scores_gemma":[0.00004307817,0.0004194587,0.001263433,0.0000164962,0.00003281164,0.0003876153,0.00004224497,0.001045715,0.9645895,0.0006148779,0.03151801,0.00002666726],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.863215,0.002781167,0.06415401,0.0002378077,0.0002910523,0.0004287774,0.003505844,0.001188047,0.06419849],"genre_scores_gemma":[0.9524874,0.002069468,0.02179311,0.00008231353,0.00002523378,0.00024422,0.001478055,0.0002231788,0.02159713],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004945965,"threshold_uncertainty_score":0.01654589,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01246656746337397,"score_gpt":0.2112080378902054,"score_spread":0.1987414704268315,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}