{"id":"W6921917788","doi":"10.1021/ja108451v.s001","title":"Kinetics of the Formation of Silver Dimers: Early Stages in the Formation of Silver Nanoparticles","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Laser-Ablation Synthesis of Nanoparticles","field":"Engineering","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Silver nanoparticle; Kinetics; Flash photolysis; Nanoparticle; Fluorescence; Aqueous solution; Molar absorptivity; Reaction rate constant; Complex formation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00008374539,0.00007932896,0.0001158834,0.00005404597,0.00001405646,0.00001013198,0.0002272945,0.00004702406,0.001576639],"category_scores_gemma":[0.0003671196,0.00004271302,0.0000548766,0.0001997749,0.00001727612,0.00052922,0.00003596653,0.00003670301,0.00005149333],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002387797,"about_ca_system_score_gemma":0.000005416617,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004773477,"about_ca_topic_score_gemma":0.00002311084,"domain_scores_codex":[0.9991466,0.00005458663,0.0003690896,0.00005178985,0.0002572897,0.0001206031],"domain_scores_gemma":[0.9991858,0.0002943923,0.000158692,0.000255031,0.0000912306,0.00001486803],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001132993,0.00005345293,0.001005413,0.0003395742,0.00001110451,2.399542e-7,0.002371971,0.004155845,0.9806168,0.00004253008,0.007854504,0.003537246],"study_design_scores_gemma":[0.0002238757,0.00002536558,0.0381786,0.0006204094,0.000008373682,5.556269e-7,0.0001507244,0.001299824,0.9585633,0.00005557562,0.0008153213,0.00005807061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9937842,0.00007843279,0.00001762069,0.0001269374,0.00001989164,0.0002248909,0.0055088,0.00002291805,0.0002163235],"genre_scores_gemma":[0.9997767,0.000004758002,0.00004489407,0.00001057333,0.00001001042,0.00002825979,0.0001053401,0.00001011164,0.000009337381],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03717318,"threshold_uncertainty_score":0.9993361,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02659938869772192,"score_gpt":0.2177528027829798,"score_spread":0.1911534140852579,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}