{"id":"W6921945996","doi":"10.1021/jo016291r.s001","title":"Influence of the β-Alkoxy Group on the Diastereoselectivity of\\nAldol Reactions of Tetrahydro-4<i>H</i>-thiopyran-4-one with\\n4-Alkoxytetrahydro-2<i>H</i>-thiopyran-3-carboxaldehydes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organic Chemistry Synthesis Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Aldol reaction; Diastereomer; Selectivity; Adduct; Enol; Trimethylsilyl; Ether","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004240781,0.0004511291,0.0001677258,0.0001889159,0.0001585992,0.0003270064,0.0003145798,0.0001617028,0.001825232],"category_scores_gemma":[0.0004267862,0.0002159892,0.0001314999,0.0001974469,0.000226244,0.0002737796,0.0002194563,0.0004201771,0.00063703],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002162665,"about_ca_system_score_gemma":0.0003339285,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00107003,"about_ca_topic_score_gemma":0.002433332,"domain_scores_codex":[0.9997615,0.00005923028,0.00002318487,0.00004030408,0.00003725855,0.00007836328],"domain_scores_gemma":[0.9997498,0.00008481812,0.00004743734,0.00002723708,0.00003770661,0.00005304751],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003881683,0.00003437301,0.0003691302,0.00007572055,0.00001905252,0.000159291,0.0001419205,0.0002339249,0.9953318,0.0003863065,0.000118213,0.002742125],"study_design_scores_gemma":[0.00001289433,0.0001373002,0.0006647903,0.000004839857,0.00001163331,0.00004810033,0.0000287838,0.0004133341,0.9976065,0.00002590563,0.001039525,0.000006455577],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9929872,0.0004566573,0.001117818,0.00007548442,0.0000272451,0.00001501126,0.0001645985,0.0000495671,0.005106419],"genre_scores_gemma":[0.9969669,0.0005944035,0.0007871377,0.00003262193,0.000009958591,0.00001273844,0.0001977152,0.00003619182,0.001362211],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001825232,"threshold_uncertainty_score":0.006106019,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02288838940120548,"score_gpt":0.2366996531293573,"score_spread":0.2138112637281518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}