{"id":"W6921998924","doi":"10.1021/jo8015192.s001","title":"A Route to 1,4-Disubstituted Aromatics and Its Application to the Synthesis of the Antibiotic Culpin","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Biochemical and biochemical processes","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Benzoates; Alkyl; Alkylation; Antibiotics; Antimicrobial; Metabolite; Allylic rearrangement; Benzoic acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002950784,0.00009136644,0.00008042129,0.000009079608,0.00004407048,0.000008976823,0.0003127066,0.00008764263,0.0001893999],"category_scores_gemma":[0.001516077,0.00004101556,0.00003993302,0.0001334868,0.00001336317,0.000002124782,0.0002547638,0.00002881771,0.0000911692],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00000576674,"about_ca_system_score_gemma":0.00002317788,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001479238,"about_ca_topic_score_gemma":0.00000607247,"domain_scores_codex":[0.9994497,0.00001424216,0.0001188346,0.0002050965,0.00009170197,0.0001204715],"domain_scores_gemma":[0.9994912,0.00003686261,0.00005150791,0.0002689053,0.00008388751,0.00006767079],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001251965,0.00001597006,0.00004643279,0.00007694792,0.0000107063,5.678424e-8,0.000008346889,9.968561e-7,0.9709945,0.00000668034,0.02444702,0.004379799],"study_design_scores_gemma":[0.00005120738,0.00002151566,0.001331069,0.000378101,0.000008351738,0.000002186109,0.000005035286,0.000008282958,0.9637753,0.00001406081,0.03432172,0.00008313249],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9481866,0.0008848204,0.0001340754,0.008037854,0.00004016342,0.001004899,0.04118545,0.00002415658,0.0005019559],"genre_scores_gemma":[0.9986346,0.000009072642,0.00005532504,0.0005128843,0.00007878589,0.00007118903,0.0005115942,0.000007966899,0.00011854],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.05044801,"threshold_uncertainty_score":0.2073796,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01209050952648391,"score_gpt":0.2302568148519848,"score_spread":0.2181663053255009,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}