{"id":"W6922004283","doi":"10.1021/ol500902p.s001","title":"Kinetic Diastereomer Differentiation in Au(III)- and\\nBi(III)-Catalyzed Benzylic Arylation: Concise and Stereocontrolled\\nSynthesis of 2‑Amino-1,1-diarylalkanes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Libraries and Information Services","field":"Arts and Humanities","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Discovery Centre","funders":"","keywords":"Stereoselectivity; Reactivity (psychology); Diastereomer; Trifluoromethanesulfonate; Kinetic energy; Chain (unit)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00004539382,0.0001572577,0.0002857265,0.0001520771,0.0001000113,0.0001528671,0.0001064916,0.00005678941,0.07029919],"category_scores_gemma":[0.0000820147,0.0001057997,0.00004317728,0.00004126105,0.0000369991,0.001213627,0.00008971225,0.00004100689,0.00008684064],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001242162,"about_ca_system_score_gemma":0.00002178687,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001739512,"about_ca_topic_score_gemma":0.0007250425,"domain_scores_codex":[0.9990769,0.0000308526,0.000416372,0.0001614284,0.0001420837,0.0001723589],"domain_scores_gemma":[0.9990472,0.0003398811,0.0003069886,0.0001599487,0.00008487017,0.00006110766],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"observational","study_design_scores_codex":[0.001569016,0.0004104683,0.03588013,0.005925735,0.0006586959,0.00001936308,0.3101124,0.000009909706,0.002604098,0.03310341,0.04299654,0.5667102],"study_design_scores_gemma":[0.02760433,0.0005394624,0.6223856,0.01158589,0.0002534724,0.00001806199,0.02132454,0.005771037,0.01249223,0.003083281,0.2922467,0.002695425],"study_design_candidate":"observational","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9680684,0.0007768775,0.000002942997,0.000518659,0.0001042233,0.000535719,0.02118141,0.00005358395,0.008758151],"genre_scores_gemma":[0.9960847,0.00002854187,0.000005832364,0.0001280614,0.0001849414,0.00009607583,0.003000725,0.00001225968,0.0004588608],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5865055,"threshold_uncertainty_score":0.9305507,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02891848734252575,"score_gpt":0.1991133160521179,"score_spread":0.1701948287095922,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}