{"id":"W6922007870","doi":"10.1021/ol4003338.s001","title":"Silver-Promoted, Palladium-Catalyzed Direct Arylation of Cyclopropanes: Facile Access to Spiro 3,3′-Cyclopropyl Oxindoles","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre in Green Chemistry and Catalysis","funders":"","keywords":"Intramolecular force; Cyclopropane; Epimer; Catalysis; Isomerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0001238826,0.0003020897,0.0003767459,0.0001597829,0.00008971701,0.00007497206,0.0005787024,0.0002052303,0.3247653],"category_scores_gemma":[0.003997149,0.0002387944,0.0001666412,0.0004566733,0.00002194924,0.000386769,0.0003298312,0.0001053614,0.001745055],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001671396,"about_ca_system_score_gemma":0.0001495729,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003933689,"about_ca_topic_score_gemma":0.00002960956,"domain_scores_codex":[0.997924,0.00003741252,0.0005457611,0.0005967282,0.0005570691,0.0003390253],"domain_scores_gemma":[0.997864,0.0004592957,0.00032474,0.0007602427,0.0003854904,0.0002062063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002089116,0.0001663246,0.002961498,0.001239579,0.0001325557,0.00001817207,0.0002406268,0.0002366129,0.8183571,0.00002303715,0.1306823,0.04573328],"study_design_scores_gemma":[0.001011352,0.00002322823,0.006173654,0.002323335,0.00003637502,0.00001597395,0.00003420546,0.0001248802,0.8385721,0.0001600164,0.1509714,0.0005534408],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.1691522,0.0005821344,0.002769602,0.001440898,0.0005769694,0.002006971,0.7195684,0.001548193,0.1023547],"genre_scores_gemma":[0.8461081,0.00001876372,0.002164366,0.0002667654,0.0009111206,0.0008576921,0.1350447,0.0002078653,0.01442058],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6769559,"threshold_uncertainty_score":0.9990322,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05353743137808949,"score_gpt":0.302750669360629,"score_spread":0.2492132379825395,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}