{"id":"W6922026082","doi":"10.1021/jo301644w.s001","title":"Challenging Deprotection\\nSteps During the Synthesis\\nof Tetra- and Pentasaccharide Fragments of the Le&lt;sup&gt;a&lt;/sup&gt;Le&lt;sup&gt;x&lt;/sup&gt; Tumor-Associated Hexasaccharide Antigen","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph","funders":"","keywords":"Glycosylation; Monosaccharide; Oligosaccharide; Glycoside; Fucose; Glycosyl; Conjugated system","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003477932,0.0005486701,0.0002378622,0.0001356827,0.0001827884,0.0002647361,0.0003057037,0.000301036,0.002565975],"category_scores_gemma":[0.0002873933,0.0001895917,0.0002336579,0.0002665783,0.0001871241,0.0004080585,0.000300602,0.001186735,0.001544993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001840971,"about_ca_system_score_gemma":0.0005857467,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004638269,"about_ca_topic_score_gemma":0.001125258,"domain_scores_codex":[0.9998119,0.00002568398,0.0000173302,0.00005483006,0.00004132318,0.00004897926],"domain_scores_gemma":[0.9998177,0.00004345509,0.00003693821,0.00004874032,0.00003491245,0.00001832514],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008892913,0.00005051237,0.00008866179,0.0001203169,0.00001039863,0.0001414963,0.00008390647,0.0002006085,0.9929026,0.0004515991,0.0001559014,0.005705099],"study_design_scores_gemma":[0.000009455382,0.0001265702,0.0003801687,0.000009014726,0.00001111665,0.0001643353,0.00001883545,0.0003900374,0.9925601,0.00009214693,0.006230022,0.000008221469],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.901086,0.002987074,0.08351886,0.0004409341,0.0003213143,0.0003478393,0.001090175,0.000265428,0.009942364],"genre_scores_gemma":[0.9402538,0.00488963,0.0391771,0.0003561614,0.00006858604,0.0003144772,0.002931922,0.0002358168,0.01177235],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002565975,"threshold_uncertainty_score":0.008584082,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01585693135337411,"score_gpt":0.2004962763386538,"score_spread":0.1846393449852797,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}