{"id":"W6922026637","doi":"10.1021/ic701657r.s001","title":"Identification of Bismuth-Thiolate-Carboxylate Clusters by Electrospray Ionization Mass Spectrometry","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organometallic Compounds Synthesis and Characterization","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"","keywords":"Electrospray ionization; Mass spectrometry; Cysteine; Bismuth; Ionization; Cluster (spacecraft); Electrospray; Extractive electrospray ionization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002367465,0.0004080931,0.0001981247,0.0009881133,0.000296658,0.0002589779,0.0004022047,0.0004606094,0.002191366],"category_scores_gemma":[0.0003591599,0.0001362677,0.0001599688,0.0003916942,0.000187487,0.0003269553,0.0001985597,0.0003652002,0.0006867452],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003718793,"about_ca_system_score_gemma":0.0002135346,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005468326,"about_ca_topic_score_gemma":0.001171422,"domain_scores_codex":[0.9998018,0.00001468681,0.00001028175,0.00005327685,0.000098196,0.00002176709],"domain_scores_gemma":[0.9998122,0.00003707042,0.00003846041,0.00001351171,0.00006429308,0.00003452889],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003519665,0.00001273694,0.0002228637,0.00002633803,0.000006389944,0.00004693731,0.00002075929,0.00004238354,0.9972819,0.0001877243,0.0001263759,0.001990406],"study_design_scores_gemma":[0.00001145611,0.00009045979,0.004353445,0.000009097762,0.00001001158,0.0003260435,0.00003193345,0.002867817,0.9875808,0.0002814155,0.004428406,0.000009185194],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9180851,0.002851382,0.06409027,0.0004681927,0.0001170146,0.0003899432,0.0034993,0.0008368276,0.009661998],"genre_scores_gemma":[0.895753,0.00151998,0.088525,0.0003449321,0.00003295787,0.0002722369,0.00379981,0.0001673207,0.009584654],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002191366,"threshold_uncertainty_score":0.007330835,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008910675636174422,"score_gpt":0.203171566783417,"score_spread":0.1942608911472426,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}