{"id":"W6922027061","doi":"10.1021/jo049254j.s001","title":"Abnormal Solvent Effects on Hydrogen Atom Abstraction. 2.\\nResolution of the Curcumin Antioxidant Controversy. The Role of\\nSequential Proton Loss Electron Transfer","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Image Processing and 3D Reconstruction","field":"Computer Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"National Research Council Canada","funders":"","keywords":"Moiety; Radical; Hydrogen atom; Methanol; Solvent; Electron transfer; Radical ion; Homolysis; Proton; Acetic acid","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002637662,0.0003222804,0.0001498673,0.0001174408,0.0001346632,0.0001929122,0.0002500606,0.0002812315,0.003363769],"category_scores_gemma":[0.0006100313,0.0001381056,0.0001504747,0.0001115335,0.0002360199,0.0003891827,0.0002083176,0.00037104,0.0005188054],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002052345,"about_ca_system_score_gemma":0.0001870039,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00129092,"about_ca_topic_score_gemma":0.0009454385,"domain_scores_codex":[0.9998055,0.00004078085,0.00001177228,0.00004594753,0.00003726441,0.00005869889],"domain_scores_gemma":[0.999698,0.0001182512,0.00006238499,0.00004136295,0.0000483295,0.00003166028],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005273172,0.00001651924,0.0004405516,0.0000946848,0.00001229563,0.00007360626,0.00004344,0.00008816878,0.9961503,0.0001302313,0.00009230067,0.002330588],"study_design_scores_gemma":[0.00001010296,0.00009328155,0.001244724,0.000003363381,0.000006159067,0.00003572178,0.00002272616,0.0004185432,0.9974627,0.0000284138,0.0006702874,0.000003902059],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9905047,0.002422923,0.00296992,0.0001860484,0.00008018329,0.00002658559,0.0005323237,0.0001407322,0.003136651],"genre_scores_gemma":[0.9965258,0.0005973306,0.0008234394,0.00003576216,0.000009714559,0.00001403673,0.0004164216,0.00001945754,0.001558041],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003363769,"threshold_uncertainty_score":0.01125288,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006114733029036267,"score_gpt":0.2096072258770034,"score_spread":0.2034924928479671,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}