{"id":"W6922042773","doi":"10.1021/om300014r.s001","title":"A Cis-Bis-Mixed-Carbene\\nRuthenium Hydride Complex:\\nAn Olefin-Selective Hydrogenation Catalyst","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Catalysis; Carbene; Hydride; Palladium; Alkene; Range (aeronautics); Hydrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000137602,0.0002943071,0.0003081124,0.000149799,0.0001488507,0.0002813849,0.0008477883,0.0003467291,0.003442454],"category_scores_gemma":[0.0001457554,0.0001686682,0.00009607154,0.0001554032,0.0001765021,0.000352509,0.0004346613,0.0005099501,0.0009182027],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006728002,"about_ca_system_score_gemma":0.0003175127,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001591173,"about_ca_topic_score_gemma":0.002754651,"domain_scores_codex":[0.9998391,0.00001153321,0.000008820151,0.00005008764,0.00004177535,0.00004874578],"domain_scores_gemma":[0.9999671,0.000004238264,0.000004945662,0.000006608315,0.000005909104,0.00001115412],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003573777,0.00007498577,0.0002973941,0.0002388333,0.00002704152,0.0001818059,0.0001044468,0.000311787,0.9867023,0.002647631,0.001697763,0.007358712],"study_design_scores_gemma":[0.00003978973,0.0001781939,0.0005532394,0.000007906384,0.00001238404,0.0001405863,0.0000195038,0.001027329,0.9897334,0.0000744207,0.008201892,0.00001139364],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9600076,0.0009490932,0.01099333,0.0003476303,0.0001348549,0.0001940956,0.0005565683,0.0007675684,0.02604925],"genre_scores_gemma":[0.9901024,0.0002787707,0.0018136,0.0000451216,0.000007700793,0.00003995403,0.0003380043,0.00004069809,0.00733393],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003442454,"threshold_uncertainty_score":0.01151621,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02771552704529649,"score_gpt":0.2430859177798623,"score_spread":0.2153703907345658,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}