{"id":"W6922052955","doi":"10.1021/ic800027m.s001","title":"Kinetics and Mechanism of Nucleophilic Addition to Nitric Oxide: Secondary Amine Diazeniumdiolation","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Kinetics; Pyrrolidine; Amine gas treating; Nucleophilic addition; Nitric oxide; Reaction mechanism; Mechanism (biology)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005382719,0.0004141791,0.0003906717,0.0002331939,0.0001937162,0.0003200318,0.0006535577,0.0003422195,0.001743048],"category_scores_gemma":[0.0007009098,0.000200426,0.0002251264,0.0001046528,0.0003311289,0.0003860489,0.0002120327,0.0005042821,0.0005988021],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004028745,"about_ca_system_score_gemma":0.0002353799,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008121228,"about_ca_topic_score_gemma":0.00104537,"domain_scores_codex":[0.9996827,0.00004676008,0.00001128779,0.0001002722,0.00009729487,0.00006172683],"domain_scores_gemma":[0.9994525,0.0002637479,0.0001033214,0.00003366552,0.0000871117,0.00005969932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002214509,0.00003830887,0.0003558004,0.0001345708,0.00001366041,0.00006815053,0.00006376333,0.0006408375,0.993706,0.0006489383,0.0001142827,0.003994251],"study_design_scores_gemma":[0.000007564727,0.0001466632,0.0008425348,0.0000046651,0.000006795835,0.00005482656,0.00001098556,0.003179585,0.9946005,0.0001094804,0.001027647,0.000008793978],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9691141,0.004486669,0.01923098,0.0001893839,0.0001017292,0.0001368451,0.0004557847,0.0002175716,0.006066862],"genre_scores_gemma":[0.9910553,0.001063583,0.004404242,0.00003980254,0.00001401142,0.00004482919,0.0001927358,0.00002265066,0.003162863],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001743048,"threshold_uncertainty_score":0.005831063,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01620967322058492,"score_gpt":0.2191327646065371,"score_spread":0.2029230913859521,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}