{"id":"W6922172631","doi":"10.1021/om900739k.s001","title":"Unprecedented Reactivity Initiated by Insertion of 2,6-Xylylisonitrile into the W−Alkyl Linkages of Cp*W(NO)(&lt;i&gt;n&lt;/i&gt;-alkyl)(η&lt;sup&gt;3&lt;/sup&gt;-CH&lt;sub&gt;2&lt;/sub&gt;CHCHMe) Complexes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Reactivity (psychology); Intramolecular force; Nucleophile; Ligand (biochemistry); Nitrogen","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002518374,0.0006178754,0.0003200815,0.0001510833,0.0002045278,0.0003798644,0.0006983901,0.0004414694,0.003045949],"category_scores_gemma":[0.0003121396,0.0002917125,0.0002352008,0.0002634198,0.0002560013,0.000467467,0.00059013,0.0009444295,0.0009777453],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003295307,"about_ca_system_score_gemma":0.000299185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009147644,"about_ca_topic_score_gemma":0.001072306,"domain_scores_codex":[0.9997459,0.00003890919,0.00001120681,0.00004809245,0.00003044383,0.0001255231],"domain_scores_gemma":[0.9999086,0.00001492612,0.00002844013,0.00001644138,0.00001095046,0.00002057423],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003119212,0.00007959442,0.0002526369,0.0002616811,0.00003212745,0.0004294118,0.0003448227,0.0006710111,0.9874157,0.003707277,0.0008388439,0.0056549],"study_design_scores_gemma":[0.00002955764,0.000533252,0.0006797861,0.00001121451,0.00001466212,0.0001641861,0.00005967106,0.0006963795,0.9914994,0.0001246162,0.00616094,0.00002635329],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9761218,0.0007009668,0.008580745,0.0001732062,0.00008802056,0.00008014493,0.0002794237,0.0003773143,0.01359836],"genre_scores_gemma":[0.993198,0.0004788396,0.001402992,0.00005752493,0.00001093678,0.00004988448,0.0002979928,0.00006439188,0.004439414],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003045949,"threshold_uncertainty_score":0.01018971,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02535674562664962,"score_gpt":0.2398079188993247,"score_spread":0.2144511732726751,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}