{"id":"W6922215815","doi":"10.1021/ja0357588.s001","title":"Diselenides and Allyl Selenides as Glutathione Peroxidase\\nMimetics. Remarkable Activity of Cyclic Seleninates Produced\\nin Situ by the Oxidation of Allyl ω-Hydroxyalkyl Selenides","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Selenide; Catalysis; Thiol; In situ; Selenium; Allyl alcohol; Sulfide; Glutathione","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001994617,0.0003435113,0.0001421397,0.000130532,0.00005989747,0.0001563909,0.0001760863,0.0002333442,0.000598066],"category_scores_gemma":[0.0001143024,0.00009065714,0.00017446,0.0001537822,0.0001605443,0.0002441637,0.000208162,0.0002801656,0.0002416663],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001596315,"about_ca_system_score_gemma":0.0001272965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002363034,"about_ca_topic_score_gemma":0.0006950334,"domain_scores_codex":[0.9999012,0.00002640026,0.000008463754,0.00002362066,0.00002174212,0.0000186428],"domain_scores_gemma":[0.999953,0.000006772639,0.00001169705,0.0000071881,0.000008598477,0.00001269061],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004199875,0.000009401095,0.00005781882,0.00003222478,0.000003903189,0.00002426361,0.00002156454,0.00004074846,0.9982733,0.0001595945,0.00001796289,0.001317209],"study_design_scores_gemma":[0.000004655619,0.0001826834,0.0002012169,0.000001793414,0.000004655881,0.00003867442,0.0000109099,0.0001277667,0.9982378,0.00002163461,0.001166528,0.000001693152],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.987969,0.003413198,0.005714722,0.0001062847,0.00004026072,0.00004799851,0.0001410586,0.00009457323,0.002472834],"genre_scores_gemma":[0.9913817,0.001663344,0.003471238,0.00002895501,0.00000704573,0.00002286826,0.00024937,0.00001359357,0.003161819],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000598066,"threshold_uncertainty_score":0.002000749,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.042665591532147,"score_gpt":0.3456077248389379,"score_spread":0.3029421333067909,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}