{"id":"W6922219526","doi":"10.1021/jacs.4c11776.s001","title":"Fluoroform\\n(CHF<sub>3</sub>) Production from CF<sub>3</sub>CHO Photolysis and\\nImplications for the Decomposition of Hydrofluoroolefins\\nand Hydrochlorofluoroolefins in the Atmosphere","year":2024,"lang":"en","type":"article","venue":"Figshare","topic":"Atmospheric Ozone and Climate","field":"Earth and Planetary Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Photodissociation; Decomposition; Atmosphere (unit); Atmospheric chemistry; Photoionization; Atmospheric pressure; Ozone; Spectroscopy; Bar (unit)","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002577628,0.0004942832,0.0001422508,0.0002511169,0.0004693287,0.0001756263,0.0003427818,0.0002954637,0.004351644],"category_scores_gemma":[0.0001912368,0.0001604268,0.0002600252,0.0002317187,0.000278687,0.0003146332,0.0002948528,0.0004517936,0.001211212],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007453092,"about_ca_system_score_gemma":0.0007475295,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.003706142,"about_ca_topic_score_gemma":0.00918857,"domain_scores_codex":[0.9997904,0.00001158708,0.000006747583,0.00005680699,0.00008175363,0.00005265992],"domain_scores_gemma":[0.9999385,0.00000699734,0.00001460177,0.00001657535,0.0000161754,0.00000715634],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007484033,0.00001883018,0.0003826995,0.00009166884,0.000003761061,0.0001069275,0.00005544043,0.0001116392,0.9916891,0.0008289621,0.0008963189,0.005739841],"study_design_scores_gemma":[0.000009258869,0.0001098009,0.001621688,0.00001193133,0.000005571756,0.0001950307,0.00002257106,0.0002609408,0.9829026,0.0000758891,0.01477449,0.00001015531],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8791305,0.001333245,0.06055292,0.0003483445,0.0001504764,0.0006523334,0.00563979,0.0008045134,0.05138775],"genre_scores_gemma":[0.9489709,0.001434476,0.02992891,0.0001656433,0.00001633775,0.0002626927,0.004356696,0.0001326871,0.01473159],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004351644,"threshold_uncertainty_score":0.01455772,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01666001585273384,"score_gpt":0.2337098775912405,"score_spread":0.2170498617385067,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}