{"id":"W6922221454","doi":"10.1021/jp900767k.s001","title":"Abundant Dipositively Charged Protonated a<sub>2</sub> and a<sub>3</sub> Ions from Diproline and Triproline","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Ion; Protonation; Delocalized electron; Disproportionation; Charge (physics)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002390273,0.0005381305,0.000241056,0.0002467271,0.0002593577,0.000346851,0.0004792847,0.0004427938,0.005594846],"category_scores_gemma":[0.0003210724,0.0002130319,0.0001706626,0.0002679589,0.0003688456,0.0005091211,0.0003755553,0.0008444102,0.0009240136],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004279116,"about_ca_system_score_gemma":0.000242648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005378667,"about_ca_topic_score_gemma":0.0005000524,"domain_scores_codex":[0.9997194,0.00002354347,0.000007784941,0.0001194854,0.000051482,0.00007822506],"domain_scores_gemma":[0.9998195,0.000041095,0.00005160232,0.00002553338,0.00002569919,0.00003663049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003721677,0.00001532602,0.000201629,0.00008286415,0.000009186788,0.0001521873,0.00007769963,0.00006439603,0.9958638,0.0005193386,0.0003321892,0.002309199],"study_design_scores_gemma":[0.00002388597,0.0001805851,0.001590976,0.000006099888,0.000008419073,0.0004024781,0.00005656168,0.0005755558,0.9933108,0.0001511948,0.003679969,0.00001345167],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9811549,0.0006097798,0.008895682,0.0001584409,0.0000877074,0.00006599359,0.000988575,0.0002337642,0.007805159],"genre_scores_gemma":[0.9839213,0.0003654508,0.006112846,0.0002234454,0.00002457132,0.00006788321,0.001459265,0.00013428,0.007691148],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005594846,"threshold_uncertainty_score":0.01871663,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01623139000047945,"score_gpt":0.2417355717700305,"score_spread":0.2255041817695511,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}