{"id":"W6922230955","doi":"10.1021/la015505x.s001","title":"Aryl Ketone Photochemistry on Monolayer Protected\\nClusters:  Study of the Norrish Type II Reaction as a Probe\\nof Conformational Mobility and for Selective Surface\\nModification","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Aryl; Monolayer; Ketone; Alkene; Excited state; Benzene; Fragmentation (computing); Reactivity (psychology)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001173166,0.0002657302,0.000156476,0.00005955152,0.00008632677,0.0001346594,0.0002302759,0.0002020052,0.0006752039],"category_scores_gemma":[0.0001049315,0.0001037841,0.0001168303,0.00009073324,0.0001507605,0.0001256575,0.0001217509,0.0002758308,0.0001511421],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001971752,"about_ca_system_score_gemma":0.00009476206,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009358449,"about_ca_topic_score_gemma":0.001224683,"domain_scores_codex":[0.9999163,0.000009982529,0.00000374553,0.00002134661,0.00002455626,0.00002409952],"domain_scores_gemma":[0.999936,0.00001578895,0.00001670528,0.000010168,0.00001182376,0.000009555344],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000230992,0.000003150066,0.00004267992,0.00001618722,0.00000197468,0.00001732294,0.00001448315,0.00002105683,0.9995252,0.00002532418,0.000008517078,0.0003010396],"study_design_scores_gemma":[0.000002365708,0.00005315734,0.0004787947,0.00000118238,0.000002451189,0.00001933212,0.000009610887,0.0002272059,0.9989404,0.000003587472,0.0002603587,0.000001445964],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9976149,0.0003873822,0.001164074,0.0000208372,0.000008038402,0.00000933308,0.00004073887,0.00002614344,0.0007284796],"genre_scores_gemma":[0.9968611,0.0003911993,0.001098684,0.00001903996,0.000002683648,0.00001075858,0.00006531559,0.000009644705,0.001541517],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009358449,"threshold_uncertainty_score":0.002258778,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03741437532292906,"score_gpt":0.2776822143902656,"score_spread":0.2402678390673366,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}