{"id":"W6922268619","doi":"10.1021/jo500927x.s001","title":"A Systematic Study of the\\nEffects of Relative Configuration,\\nProtecting Group, and Enolate Type on the Diastereoselectivities of\\nAldol Reactions of a Chiral Ethyl Ketone with 2‑Methylpropanal","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Diverse Scientific and Economic Studies","field":"Economics, Econometrics and Finance","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Aldol reaction; Transmetalation; Diastereomer; Adduct; Ketone; Stereoselectivity; Aldol condensation","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006219127,0.000496873,0.0002654592,0.0004378437,0.0002355741,0.0002882116,0.0002974612,0.0001530994,0.001334426],"category_scores_gemma":[0.0006439384,0.0002405564,0.0002246377,0.0004599076,0.0003226348,0.0004078535,0.0003024135,0.0004028752,0.0004459819],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002064168,"about_ca_system_score_gemma":0.0003490447,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005860207,"about_ca_topic_score_gemma":0.001471173,"domain_scores_codex":[0.9997138,0.00006407179,0.0000397394,0.0000629022,0.00005892576,0.00006064217],"domain_scores_gemma":[0.9995616,0.0001521235,0.00007483685,0.00008529358,0.00008207783,0.00004400128],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003122171,0.0001107975,0.001073488,0.0001721055,0.00002615563,0.0001097666,0.000117948,0.0003215378,0.9846102,0.0001763307,0.0001387503,0.01283068],"study_design_scores_gemma":[0.00001506444,0.0004519005,0.003525887,0.00001451255,0.00003958488,0.0001217793,0.00004950206,0.0004579074,0.9924477,0.00002891798,0.002829486,0.00001772706],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9902199,0.002281904,0.002469482,0.00006504718,0.00002032069,0.0000765933,0.000300458,0.00006719537,0.004499192],"genre_scores_gemma":[0.9879847,0.004919481,0.003794166,0.00007178081,0.00002437679,0.00007001904,0.0006103071,0.00007936331,0.002445927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001334426,"threshold_uncertainty_score":0.00446409,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05700249039947227,"score_gpt":0.2089494090642431,"score_spread":0.1519469186647709,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}