{"id":"W6940520813","doi":"10.1021/jo4017524.s001","title":"Scandium Triflate-Catalyzed\\nNucleophilic Additions\\nto Indolylmethyl Meldrum’s Acid Derivatives via a Gramine-Type\\nFragmentation: Synthesis of Substituted Indolemethanes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Mycorrhizal Fungi and Plant Interactions","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Moiety; Nucleophile; Trifluoromethanesulfonate; Reaction conditions; Yield (engineering); Scandium","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002621926,0.0005196641,0.0001768456,0.0002494558,0.0001790006,0.0001435593,0.0004949258,0.0004783004,0.001815436],"category_scores_gemma":[0.0001523105,0.0001760275,0.0003020102,0.0001990861,0.0002139993,0.0003483458,0.0002550293,0.0004026092,0.0009096694],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002812717,"about_ca_system_score_gemma":0.0003503031,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007399741,"about_ca_topic_score_gemma":0.002000145,"domain_scores_codex":[0.9998719,0.00002681463,0.00001032244,0.00002015877,0.00001647833,0.00005429369],"domain_scores_gemma":[0.9999334,0.000009207594,0.000019157,0.00001054575,0.00001014482,0.00001756162],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001843008,0.00006199007,0.0001048656,0.000200173,0.0000154,0.0003094961,0.0001501638,0.0003452407,0.9904155,0.00127437,0.0002316237,0.006706965],"study_design_scores_gemma":[0.00003363007,0.0004770548,0.0006404844,0.00001420414,0.00001167256,0.0002396444,0.00002281417,0.0005961994,0.9927565,0.00008534271,0.005104057,0.00001839752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9571117,0.002963715,0.02093223,0.00022783,0.0001465496,0.0001634673,0.0004294032,0.0002998291,0.01772533],"genre_scores_gemma":[0.9820197,0.001719262,0.01055901,0.00006750679,0.00001526331,0.00006828939,0.0003277731,0.00003878383,0.005184388],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001815436,"threshold_uncertainty_score":0.006073236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02397660244524306,"score_gpt":0.2263583966828397,"score_spread":0.2023817942375967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}