{"id":"W6940673443","doi":"10.11575/prism/35301","title":"Enantiocomplementary Enzymatic Resolution of the Chiral Auxiliary cis,cis-6-(2,2-Dimethylpropanamido)spiro-[4.4]nonan-1-ol and the Moleuclar Basis for the High Enantioselectivity of Subtilisin Carlsberg","year":2004,"lang":"en","type":"other","venue":"PRISM (University of Calgary)","topic":"Mycorrhizal Fungi and Plant Interactions","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Subtilisin; Chiral auxiliary; Resolution (logic); Enzyme; Kinetic resolution; Basis (linear algebra); Chiral stationary phase; Enantiomer; Enzyme catalysis","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002707606,0.0004219032,0.0001714052,0.0001898517,0.000135989,0.0003355418,0.0004883696,0.0001945087,0.00249261],"category_scores_gemma":[0.0001781714,0.0001449681,0.0001189585,0.0001365226,0.000201524,0.0001963082,0.0004197189,0.0006758271,0.0009977462],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003472155,"about_ca_system_score_gemma":0.0003194956,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005624316,"about_ca_topic_score_gemma":0.001229829,"domain_scores_codex":[0.9998115,0.00003508068,0.00001391876,0.00003223651,0.00006827673,0.00003897792],"domain_scores_gemma":[0.9999043,0.0000123047,0.00003119864,0.00002082945,0.00001273842,0.00001854027],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009836653,0.00003322171,0.00006589704,0.00003718059,0.000002553196,0.0001113448,0.00001165437,0.00007125263,0.993799,0.0007273142,0.0002121749,0.004829874],"study_design_scores_gemma":[0.00001516181,0.00005894065,0.0002503832,0.000003338928,0.000002762309,0.0001439442,0.000005122271,0.0003068438,0.9941509,0.00007255599,0.004986767,0.000003209914],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9262686,0.005594198,0.02570807,0.0006377084,0.000344697,0.00008805627,0.0007387236,0.000687575,0.03993228],"genre_scores_gemma":[0.9603314,0.001728299,0.01584483,0.0001520918,0.00003961487,0.00003764586,0.0009233161,0.0001091417,0.02083355],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00249261,"threshold_uncertainty_score":0.008338571,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007448665959558205,"score_gpt":0.1752077402398056,"score_spread":0.1677590742802474,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}