{"id":"W6940738837","doi":"10.1021/ja105194s.s001","title":"Controlled and Chemoselective Reduction of Secondary Amides","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Mycorrhizal Fungi and Plant Interactions","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal; Stantec (Canada)","funders":"","keywords":"Reductive amination; Amide; Moiety; Amine gas treating; Iminium; Triethylsilane; Electrophile; Hydride","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000243457,0.0008059284,0.0002730278,0.0002343878,0.0001568317,0.0002030094,0.0004166416,0.0003529248,0.001510586],"category_scores_gemma":[0.0001325376,0.0001568166,0.0003294736,0.0001159397,0.0002329765,0.0003243187,0.0003847484,0.0006010171,0.001132058],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002098297,"about_ca_system_score_gemma":0.0001535489,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001624055,"about_ca_topic_score_gemma":0.0004957063,"domain_scores_codex":[0.9997262,0.00003297168,0.00001986899,0.0000791831,0.00008754562,0.00005410421],"domain_scores_gemma":[0.9998995,0.00001602378,0.00003509926,0.0000149368,0.00002050247,0.00001402236],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001675488,0.000007991625,0.00002570083,0.00006971108,0.000005209373,0.00006325445,0.00001618546,0.00005602196,0.9970247,0.0001487189,0.00007106893,0.002494683],"study_design_scores_gemma":[0.000005227005,0.00008376443,0.0003138895,0.000004678456,0.000007837584,0.0002225965,0.000006223635,0.0001514974,0.9944884,0.00004725362,0.00466284,0.000005772925],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.805443,0.01438016,0.1447599,0.0004314781,0.0004087072,0.0003493842,0.0009696442,0.0008550729,0.03240259],"genre_scores_gemma":[0.9571791,0.004012314,0.02892051,0.0001634084,0.00009363773,0.000104054,0.000614045,0.0001102793,0.00880272],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001510586,"threshold_uncertainty_score":0.005053401,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0144017599279358,"score_gpt":0.2037743689103956,"score_spread":0.1893726089824598,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}