{"id":"W6959286545","doi":"10.1021/ol802142k.s001","title":"Chemoselective Oxygen-Centered Radical Cyclizations onto Silyl Enol Ethers","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Botanical Studies and Applications","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Chemoselectivity; Silylation; Alkene; Enol; Substrate (aquarium); Silyl enol ether; Enol ether","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.00001801235,0.00009387262,0.00009720179,8.421e-7,0.0002450232,0.00002557323,0.0002032211,0.0000752485,0.08963756],"category_scores_gemma":[0.0002800099,0.00002852216,0.00007546773,0.0001565338,0.00001588187,0.00005522031,0.00008459979,0.00005639424,0.002031772],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004009651,"about_ca_system_score_gemma":0.000003218365,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004099678,"about_ca_topic_score_gemma":0.0003909852,"domain_scores_codex":[0.9993008,0.00002026884,0.0001173271,0.0002325634,0.0001109607,0.0002180379],"domain_scores_gemma":[0.999507,0.0002303743,0.00004664011,0.0000502937,0.00006478415,0.0001009588],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00001376359,0.0001850049,0.0002698178,0.00000565546,0.00003887535,0.000001435174,0.00005490168,4.298799e-7,0.06717265,0.0001486233,0.6600928,0.272016],"study_design_scores_gemma":[0.0001161426,0.00004486521,0.03084651,0.00009943946,0.000003418052,0.000001175967,0.00002327321,0.000007081437,0.002100963,0.0001331929,0.9665049,0.0001189858],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"dataset","genre_gemma":"empirical","genre_scores_codex":[0.3239043,0.002105323,0.00003128043,0.07451153,0.0002038867,0.002926445,0.5552474,0.001360624,0.03970926],"genre_scores_gemma":[0.9933711,0.00003262248,0.00002564426,0.0007661346,0.0002844375,0.0002817535,0.004681921,0.000001630617,0.0005548037],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6694668,"threshold_uncertainty_score":0.9987453,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04673949336539081,"score_gpt":0.2378540057600301,"score_spread":0.1911145123946393,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}