{"id":"W6959333477","doi":"10.1021/jo501134d.s001","title":"Organoboron-Based Allylation\\nApproach to the Total\\nSynthesis of the Medium-Ring Dilactone (+)-Antimycin A<sub>1b</sub>","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Pasture and Agricultural Systems","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Yield (engineering); Ring (chemistry); Stereoselectivity; Amide; Potassium; Lactone; Sequence (biology)","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001268192,0.0004532689,0.0001878236,0.0002928896,0.0002267481,0.0002473635,0.0003273923,0.0001733673,0.003367445],"category_scores_gemma":[0.00009977198,0.0001286022,0.0002020938,0.0002645492,0.0001750235,0.0002173164,0.0004855261,0.0006151004,0.00209374],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000468991,"about_ca_system_score_gemma":0.0008026593,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009963888,"about_ca_topic_score_gemma":0.00326481,"domain_scores_codex":[0.9999052,0.000009718989,0.000007326028,0.00002751037,0.00002093094,0.000029227],"domain_scores_gemma":[0.9999528,0.000003535153,0.0000100557,0.00000853751,0.00000951014,0.00001554945],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001136804,0.0000690907,0.0001207128,0.0002363631,0.00001444063,0.0001683017,0.00006474669,0.0003971015,0.9787403,0.001803805,0.0005226537,0.01774878],"study_design_scores_gemma":[0.00001514591,0.0002925179,0.000393921,0.00001103533,0.00001533096,0.0001959687,0.00001879367,0.0006410644,0.971082,0.0001743613,0.02714943,0.00001056438],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8395754,0.004552885,0.09010614,0.0003438485,0.0003262118,0.0005209709,0.00212858,0.001472064,0.06097402],"genre_scores_gemma":[0.9420103,0.002521043,0.03162568,0.0001543625,0.0000309479,0.0001687319,0.001498682,0.0001684126,0.02182165],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003367445,"threshold_uncertainty_score":0.01126528,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02424280032741272,"score_gpt":0.1921157862191675,"score_spread":0.1678729858917548,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}