{"id":"W6959382637","doi":"10.1021/ol901896c.s001","title":"Total Synthesis of Oidiodendrolides and Related Norditerpene Dilactones from a Common Precursor: Metabolites CJ-14,445, LL-Z1271γ, Oidiolactones A, B, C, and D, and Nagilactone F","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Biological Activity of Diterpenoids and Biflavonoids","field":"Biochemistry, Genetics and Molecular Biology","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Total synthesis; Enantioselective synthesis; Lactone; Catalysis; Tricyclic","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009046713,0.0003126361,0.0005044181,0.00005197701,0.000092698,0.00005680788,0.0001504498,0.0003808402,0.002285368],"category_scores_gemma":[0.0006744192,0.0002058894,0.00009667317,0.00006148126,0.0001409197,0.00003786272,0.0004081214,0.0001128265,0.00002189295],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000006066147,"about_ca_system_score_gemma":0.00001837128,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005714258,"about_ca_topic_score_gemma":0.00003016246,"domain_scores_codex":[0.9985604,0.0001254224,0.0003098269,0.0005957441,0.0001245232,0.0002840949],"domain_scores_gemma":[0.9989187,0.0003462473,0.0001990209,0.0002923595,0.00007743994,0.0001662286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002415699,0.0001076407,0.006557666,0.0001151149,0.0002188503,0.000007479594,0.00006143432,1.522835e-7,0.9446927,0.0000130684,0.001895234,0.04608909],"study_design_scores_gemma":[0.001033492,0.0005449969,0.1631192,0.0008574702,0.0001052386,0.00009526986,0.0000420815,0.00001921159,0.8232978,0.0004340551,0.00985284,0.0005983127],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9461938,0.008659241,0.000002363892,0.0003367223,0.00003600074,0.00019666,0.0442024,0.00002385574,0.0003489558],"genre_scores_gemma":[0.9951322,0.0009266637,0.0001987545,0.00005737977,0.0001019364,0.00005308031,0.003242329,0.00002531016,0.0002623496],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1565616,"threshold_uncertainty_score":0.9986266,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01062192588357995,"score_gpt":0.2232829767038351,"score_spread":0.2126610508202552,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}