{"id":"W6959389152","doi":"10.1021/acs.orglett.5b00452.s001","title":"Synthesis of Pyrido[2,1‑<i>b</i>]quinazolin-11-ones\\nand Dipyrido[1,2-a:2′,3′‑<i>d</i>]pyrimidin-5-ones\\nby Pd/DIBPP-Catalyzed Dearomatizing Carbonylation","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Peanut Plant Research Studies","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Carbonylation; Yield (engineering); Palladium; Catalysis; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0008706815,0.00103486,0.00140214,0.0002342901,0.0009974662,0.0002857899,0.001686968,0.0005926111,0.01756438],"category_scores_gemma":[0.006358427,0.0004726017,0.0006597349,0.001258445,0.0002574236,0.001011311,0.001152047,0.0003273197,0.0007380132],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003431214,"about_ca_system_score_gemma":0.0001398902,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005815459,"about_ca_topic_score_gemma":0.001276247,"domain_scores_codex":[0.9928983,0.0005102165,0.001248226,0.001549746,0.001883982,0.001909522],"domain_scores_gemma":[0.9928146,0.004191458,0.0009300238,0.0006357206,0.0007696761,0.0006585341],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001417444,0.0002473407,0.000656627,0.0002891152,0.0001859233,0.00006573441,0.0001783273,0.00001089622,0.8895701,0.0002903079,0.09194606,0.01641784],"study_design_scores_gemma":[0.00177035,0.0006004332,0.3277529,0.007194984,0.0002806079,0.0001122276,0.0001785662,0.0004101612,0.2336934,0.0004925989,0.424726,0.002787709],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8908734,0.004124797,0.000002388154,0.001988798,0.0002697373,0.001406858,0.08993106,0.0005453171,0.01085766],"genre_scores_gemma":[0.9771459,0.0006370724,0.00009167854,0.00006484927,0.0009273136,0.0006332723,0.01865397,0.00001846433,0.001827492],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.6558767,"threshold_uncertainty_score":0.9997725,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03653942229061093,"score_gpt":0.2403326772502835,"score_spread":0.2037932549596726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}