{"id":"W6959389152","doi":"10.1021/acs.orglett.5b00452.s001","title":"Synthesis of Pyrido[2,1‑<i>b</i>]quinazolin-11-ones\\nand Dipyrido[1,2-a:2′,3′‑<i>d</i>]pyrimidin-5-ones\\nby Pd/DIBPP-Catalyzed Dearomatizing Carbonylation","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Peanut Plant Research Studies","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Carbonylation; Yield (engineering); Palladium; Catalysis; Carbon monoxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001235195,0.0003639044,0.0003332861,0.00013799,0.0001897889,0.0001844888,0.0004248285,0.0001952878,0.004258112],"category_scores_gemma":[0.00008707873,0.0001742397,0.000174729,0.0001606518,0.00009325525,0.0001874988,0.0002140771,0.0003540809,0.001802076],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003559086,"about_ca_system_score_gemma":0.0003729541,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006553177,"about_ca_topic_score_gemma":0.00148874,"domain_scores_codex":[0.9999064,0.000007048149,0.000007754695,0.00002795488,0.00001531386,0.00003553863],"domain_scores_gemma":[0.9999615,0.000002801972,0.000006777736,0.000006311993,0.000007702936,0.00001479701],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000198241,0.00008102316,0.0001560513,0.0004953534,0.00001729976,0.0003778555,0.00008169944,0.0005149382,0.9826139,0.002027533,0.001051377,0.01238476],"study_design_scores_gemma":[0.0001086502,0.0007751232,0.0015451,0.00002082404,0.00002478048,0.0004449413,0.00003468971,0.0009899219,0.9570277,0.0001994928,0.03879573,0.00003314867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9207987,0.009499477,0.02230597,0.0003461204,0.0003943562,0.0007166889,0.004753518,0.0008512929,0.04033383],"genre_scores_gemma":[0.9638946,0.004157085,0.01202324,0.0001142263,0.00002899039,0.0002997986,0.001981741,0.00007069967,0.01742962],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004258112,"threshold_uncertainty_score":0.01424485,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03653942229061093,"score_gpt":0.2403326772502835,"score_spread":0.2037932549596726,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}