{"id":"W6959392904","doi":"10.1021/jo302142v.s001","title":"Aldol Reactions with Kinetic\\nResolution: Scope and\\nLimitations of Ketal- and Dithioketal-Protected β‑Ketoaldehydes","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Genetic and Environmental Crop Studies","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Enantiopure drug; Aldol reaction; Ketone; Adduct; Aldehyde; Enantioselective synthesis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000875915,0.0006979852,0.0002774402,0.0004886395,0.0002443572,0.000372404,0.0004778343,0.0002662125,0.001202928],"category_scores_gemma":[0.000566181,0.0002944261,0.0002728954,0.0004872141,0.0003771909,0.0006960236,0.0004307975,0.0007310142,0.0006694209],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004817457,"about_ca_system_score_gemma":0.0004283452,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001238064,"about_ca_topic_score_gemma":0.002658676,"domain_scores_codex":[0.9995074,0.0001060306,0.00005746369,0.00009927263,0.00009143924,0.0001384334],"domain_scores_gemma":[0.9997792,0.00004742941,0.00003865133,0.00004801597,0.00004707926,0.0000397351],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000283143,0.0001188579,0.0003915868,0.0001989132,0.00002800409,0.0001179333,0.0003091176,0.0005936557,0.9887289,0.001353974,0.0001443093,0.007731625],"study_design_scores_gemma":[0.00001258913,0.0001975544,0.0004087475,0.000005282298,0.00001061745,0.00007680522,0.00003746305,0.0003134049,0.9973871,0.00005552316,0.00148549,0.000009455501],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9702036,0.0024138,0.0168511,0.000120141,0.00002819678,0.0001388992,0.0004595896,0.0002467388,0.00953806],"genre_scores_gemma":[0.9850952,0.002704185,0.008039678,0.00005875173,0.00001058896,0.00006978085,0.0005157187,0.00006642369,0.003439629],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001238064,"threshold_uncertainty_score":0.004632354,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03117428833357471,"score_gpt":0.1890791596417794,"score_spread":0.1579048713082047,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}