{"id":"W6959500837","doi":"10.1021/ol900185n.s001","title":"A Direct Phosphine-Mediated Synthesis of Pyrroles from Acid Chlorides and α,β-Unsaturated Imines","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"","keywords":"Reaction conditions; Range (aeronautics); Phosphine; Yield (engineering); Oxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002410073,0.0006649544,0.0002602383,0.0002712989,0.0002072836,0.0002200501,0.0005009586,0.0004640119,0.002088364],"category_scores_gemma":[0.0002070939,0.0002740726,0.0003009332,0.0001941585,0.0002095685,0.0005439317,0.0004001685,0.0008250995,0.001283852],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003095212,"about_ca_system_score_gemma":0.0003757929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002767151,"about_ca_topic_score_gemma":0.0006257452,"domain_scores_codex":[0.9998311,0.00002198483,0.00001710522,0.00004836757,0.00004308273,0.00003835242],"domain_scores_gemma":[0.9999115,0.0000144237,0.00002790503,0.00001318184,0.00001411871,0.00001885962],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004719587,0.00003574817,0.00004755805,0.0002618246,0.00001073432,0.0002007854,0.00006376965,0.0003735743,0.9890261,0.001204889,0.0001760946,0.008551743],"study_design_scores_gemma":[0.00001906624,0.0002738514,0.0002102416,0.000007563514,0.000008316852,0.0002316539,0.000007266203,0.0004686941,0.9930479,0.00009023032,0.005622676,0.0000126366],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7871168,0.009617292,0.1632854,0.0005327552,0.000279435,0.000621434,0.001326284,0.001270845,0.03594975],"genre_scores_gemma":[0.9262105,0.003456374,0.05826994,0.0001083587,0.00002877895,0.0001843604,0.0004713197,0.0001024654,0.01116778],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002088364,"threshold_uncertainty_score":0.00698626,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01888025717701796,"score_gpt":0.2012577027857288,"score_spread":0.1823774456087108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}