{"id":"W6959521692","doi":"10.1021/ja8077895.s001","title":"The Tandem Cope-Type Hydroamination/[2,3]-Rearrangement Sequence: A Strategy to Favor the Formation of Intermolecular Hydroamination Products and Enable Difficult Cyclizations","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Legal and Regulatory Analysis","field":"Social Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Hydroamination; Tandem; Intermolecular force; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005624255,0.0007266942,0.0003935972,0.000532172,0.0006268286,0.0004540867,0.0007144865,0.0009143314,0.01315829],"category_scores_gemma":[0.0008397199,0.0004411837,0.0004675812,0.0004304873,0.0005864777,0.001474264,0.0007032306,0.001745824,0.0047875],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000262688,"about_ca_system_score_gemma":0.000857716,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004304559,"about_ca_topic_score_gemma":0.001213197,"domain_scores_codex":[0.9994987,0.00006911252,0.00003887294,0.0001453498,0.0001148646,0.0001330843],"domain_scores_gemma":[0.9995702,0.00006845444,0.00008360454,0.0001138337,0.00008358859,0.00008033915],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000762912,0.0003858353,0.0008328258,0.0005456373,0.00007874639,0.001626548,0.0004147689,0.002333347,0.9010609,0.01231042,0.009113166,0.07053489],"study_design_scores_gemma":[0.0001833031,0.001907543,0.000989354,0.00004661641,0.00003931512,0.001318861,0.0001184666,0.00309677,0.9543383,0.001463588,0.03642246,0.00007538443],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6691846,0.002494267,0.1834352,0.002913425,0.001146066,0.002419283,0.003043374,0.004360684,0.131003],"genre_scores_gemma":[0.9067787,0.001836245,0.06323743,0.0009469124,0.0001340909,0.0006536555,0.001283354,0.000422648,0.02470692],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01315829,"threshold_uncertainty_score":0.04401886,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04190796617141469,"score_gpt":0.2964192793770234,"score_spread":0.2545113132056088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}