{"id":"W6959521692","doi":"10.1021/ja8077895.s001","title":"The Tandem Cope-Type Hydroamination/[2,3]-Rearrangement Sequence: A Strategy to Favor the Formation of Intermolecular Hydroamination Products and Enable Difficult Cyclizations","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Legal and Regulatory Analysis","field":"Social Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Hydroamination; Tandem; Intermolecular force; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002719026,0.00007142906,0.0000750769,0.00004209929,0.0007113455,0.000107679,0.0002076517,0.00004393126,0.0009685223],"category_scores_gemma":[0.00134725,0.000033832,0.00002682124,0.0005624531,0.00006227255,0.0003215797,0.00005104737,0.00003668142,0.00006533093],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007750365,"about_ca_system_score_gemma":0.00009550126,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000458455,"about_ca_topic_score_gemma":0.0004325664,"domain_scores_codex":[0.9990753,0.0001546411,0.0001700141,0.0001376069,0.0003128235,0.0001496142],"domain_scores_gemma":[0.9990692,0.0001124065,0.0001233926,0.0001567377,0.0004917776,0.00004644854],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00007886905,0.0003821079,0.0003734083,0.0004720532,0.0003944886,0.00001130597,0.08458999,0.001827271,0.1604015,0.04481161,0.3727495,0.3339079],"study_design_scores_gemma":[0.0006849236,0.0003295742,0.00701849,0.001571786,0.0001347301,0.000004732939,0.009441721,0.003184998,0.07149584,0.001979564,0.9036008,0.000552876],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8452003,0.002970301,0.0008179669,0.07045769,0.0006392529,0.007785119,0.01766711,0.0003801335,0.05408211],"genre_scores_gemma":[0.9958814,0.00003328848,0.000008068168,0.00005108453,0.00006659697,0.00007844612,0.0006979802,0.000004782572,0.003178393],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5308512,"threshold_uncertainty_score":0.9999447,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04190796617141469,"score_gpt":0.2964192793770234,"score_spread":0.2545113132056088,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}