{"id":"W6959568458","doi":"10.1021/ic200503d.s002","title":"Reactions of the Bis(dialkylphosphino)methane Complexes Pd<sub>2</sub>X<sub>2</sub>(μ-R<sub>2</sub>PCH<sub>2</sub>PR<sub>2</sub>)<sub>2</sub> (X = halogen, R = Me or Et) with H<sub>2</sub>S, S<sub>8</sub>, COS, and CS<sub>2</sub>; Detection of Reaction Intermediates","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Plant pathogens and resistance mechanisms","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Yield (engineering); Decarbonylation; Sulfur; Nuclear magnetic resonance spectroscopy; Reaction intermediate; Reaction mechanism","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002479907,0.0003662471,0.00012304,0.0002165661,0.00019827,0.0001448168,0.0006005269,0.0002801351,0.004644976],"category_scores_gemma":[0.0002852399,0.0001748343,0.0001316854,0.0002242803,0.000197371,0.0002409241,0.0003017978,0.0005714023,0.0005969091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004520096,"about_ca_system_score_gemma":0.0003333392,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00232508,"about_ca_topic_score_gemma":0.002088038,"domain_scores_codex":[0.9998224,0.00002699944,0.000006498424,0.00005016971,0.00003635032,0.00005745637],"domain_scores_gemma":[0.999892,0.0000269146,0.00002215151,0.00002408407,0.00001105279,0.00002369825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006407868,0.00003368119,0.0004779352,0.00008417314,0.00001378423,0.00007428268,0.0001097353,0.0002287033,0.9936957,0.001306099,0.0003050499,0.003030156],"study_design_scores_gemma":[0.00001115914,0.0001432408,0.0008708321,0.000002214152,0.000006206729,0.00004488248,0.00002469548,0.0008582568,0.9965692,0.00006244022,0.001402669,0.000004240476],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9806542,0.0003832586,0.01173138,0.0001520868,0.00003024384,0.0000411039,0.0005387226,0.0002192263,0.006249714],"genre_scores_gemma":[0.9894218,0.0002349732,0.003759547,0.000031391,0.000005963988,0.00004538663,0.0006331057,0.00003125348,0.005836564],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004644976,"threshold_uncertainty_score":0.01553905,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02396182851281943,"score_gpt":0.2141125749095303,"score_spread":0.1901507463967108,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}