{"id":"W6959616698","doi":"10.1021/ja808862w.s001","title":"Selective C−H Activation α to Primary Amines. Bridging Metallaaziridines for Catalytic, Intramolecular α-Alkylation","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Powdery Mildew Fungal Diseases","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Intramolecular force; Bridging (networking); Primary (astronomy); Chaperone (clinical); HEK 293 cells","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002057897,0.0006275118,0.0002279931,0.0001990937,0.0002091334,0.0001222252,0.000465098,0.0004498661,0.003374223],"category_scores_gemma":[0.0002278132,0.0002087829,0.0001701297,0.0001593054,0.0002413007,0.0003667587,0.0002894005,0.0006528616,0.00122153],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003285821,"about_ca_system_score_gemma":0.0001309721,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005589403,"about_ca_topic_score_gemma":0.001240588,"domain_scores_codex":[0.9998598,0.00001540869,0.000008838244,0.00004825032,0.00003124353,0.00003645653],"domain_scores_gemma":[0.9999321,0.00001810317,0.00001782291,0.00001113576,0.00001119515,0.000009620851],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001133011,0.00001516747,0.00005309509,0.0002430698,0.000008532483,0.00009988511,0.00004336629,0.00009869468,0.9906737,0.0004095971,0.0007876239,0.007454058],"study_design_scores_gemma":[0.00003064413,0.0002291757,0.0004374275,0.00000915553,0.000007187122,0.0002322346,0.00001254348,0.0003826477,0.9914301,0.0000976575,0.007123325,0.000007812522],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7985664,0.01667887,0.1117732,0.001501889,0.0007181142,0.0007133764,0.001964316,0.002346493,0.06573733],"genre_scores_gemma":[0.9741344,0.003420875,0.01167271,0.0002459742,0.00006233009,0.0001659068,0.0006933498,0.00007940149,0.00952515],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003374223,"threshold_uncertainty_score":0.01128787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02834055663820359,"score_gpt":0.2293773261550822,"score_spread":0.2010367695168786,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}