{"id":"W6959694077","doi":"10.1021/ja8094075.s001","title":"Cross Coupling Reactions of Chiral Secondary Organoboronic Esters With Retention of Configuration","year":2016,"lang":"en","type":"article","venue":"Figshare","topic":"Plant Pathogens and Resistance","field":"Agricultural and Biological Sciences","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Pinacol; Trichlorosilane; Styrene; Diglyme; Borane; Yield (engineering); Hydroboration; Inert gas; Mesityl oxide","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007355406,0.001358502,0.0006070817,0.000544439,0.0003651495,0.0003571909,0.0005422669,0.0005746594,0.007643328],"category_scores_gemma":[0.000529869,0.0003432794,0.0006482861,0.0005207843,0.0002121122,0.0005096605,0.0006595624,0.0009115986,0.00311397],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005893579,"about_ca_system_score_gemma":0.0004446868,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003966291,"about_ca_topic_score_gemma":0.0008503664,"domain_scores_codex":[0.9993953,0.00009461405,0.00004912695,0.0001186879,0.00009476722,0.0002475979],"domain_scores_gemma":[0.9996494,0.00004343477,0.00004960388,0.0000816251,0.00008949507,0.00008641381],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001696361,0.00006972853,0.00009481272,0.0001415193,0.00003044001,0.0004194731,0.00004648032,0.0002102844,0.9920846,0.0009777508,0.0003100464,0.005445301],"study_design_scores_gemma":[0.00001253992,0.0002090059,0.0001614551,0.000007046245,0.00001850594,0.0003162891,0.000007468575,0.0001972625,0.9947671,0.00008951284,0.004206203,0.000007643835],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8561676,0.004855506,0.09407313,0.0003909082,0.0008321044,0.0008350277,0.001721355,0.001239397,0.03988486],"genre_scores_gemma":[0.9270152,0.003820125,0.03970444,0.0004084793,0.0001449025,0.0004168406,0.001992513,0.0003462811,0.02615122],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007643328,"threshold_uncertainty_score":0.0255695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02522955064296018,"score_gpt":0.2153193933341071,"score_spread":0.1900898426911469,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}