{"id":"W6986202128","doi":"","title":"Part I: Mechanistic Insight in Alkyl-Alkyl and Aryl-Aryl Negishi Cross-Coupling
\\nPart II: Large Scale Synthesis of NHC Precursors: 2,6-DI(3-Pentyl) Aniline and 2,6-DI 
\\n(4-Heptyl) Aniline","year":2016,"lang":"en","type":"other","venue":"YorkSpace (York University)","topic":"","field":"","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Negishi coupling; Zincate; Halide; Reagent; Moiety; Aniline; Alkyl; Aryl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.001136023,0.002095532,0.003000991,0.004443741,0.0006105085,0.0002588904,0.001685761,0.002137165,0.002513542],"category_scores_gemma":[0.0005020781,0.002197809,0.0004549547,0.003108235,0.001648236,0.000843823,0.001443465,0.001330197,0.0004429077],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007277725,"about_ca_system_score_gemma":0.0005219005,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001695714,"about_ca_topic_score_gemma":0.04653878,"domain_scores_codex":[0.9921646,0.0002806109,0.0011589,0.003021268,0.001258578,0.002116022],"domain_scores_gemma":[0.9936585,0.0008200229,0.00197444,0.002140186,0.0003811522,0.001025685],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"not_applicable","study_design_scores_codex":[0.01400792,0.01171516,0.2921252,0.008803727,0.006534346,0.004213227,0.01114636,0.001177819,0.03039466,0.02156451,0.5946163,0.003700795],"study_design_scores_gemma":[0.01052356,0.0007726239,0.005218363,0.008145612,0.001723928,0.0000864289,0.002175325,0.002071634,0.004554513,0.0002549018,0.9602028,0.004270289],"study_design_candidate":"not_applicable","study_design_consensus":"not_applicable","genre_codex":"empirical","genre_gemma":"other","genre_scores_codex":[0.6600854,0.01609368,0.001528706,0.001126796,0.002604001,0.008239461,0.01501781,0.003608546,0.2916955],"genre_scores_gemma":[0.366381,0.008975326,0.001076305,0.00008847305,0.00109968,0.00004716557,0.0005852193,0.003036965,0.6187099],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.3655865,"threshold_uncertainty_score":0.9991786,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00984621805941393,"score_gpt":0.2223153717647388,"score_spread":0.2124691537053248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}