{"id":"W6986202128","doi":"","title":"Part I: Mechanistic Insight in Alkyl-Alkyl and Aryl-Aryl Negishi Cross-Coupling
\\nPart II: Large Scale Synthesis of NHC Precursors: 2,6-DI(3-Pentyl) Aniline and 2,6-DI 
\\n(4-Heptyl) Aniline","year":2016,"lang":"en","type":"other","venue":"YorkSpace (York University)","topic":"","field":"","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Negishi coupling; Zincate; Halide; Reagent; Moiety; Aniline; Alkyl; Aryl","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001759184,0.0003752606,0.0001388985,0.00007778753,0.0001172307,0.0002790893,0.0003655764,0.0003112597,0.003727073],"category_scores_gemma":[0.0000977387,0.0001288294,0.0001914695,0.00007884254,0.0002528674,0.0005996099,0.0003164858,0.0005719782,0.0007687368],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003924157,"about_ca_system_score_gemma":0.0002473208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003022547,"about_ca_topic_score_gemma":0.0004870542,"domain_scores_codex":[0.9999238,0.000009839214,0.000005412721,0.00001700592,0.00001878408,0.00002507748],"domain_scores_gemma":[0.9999584,0.000009293417,0.00001243279,0.000006344369,0.000007170323,0.000006358215],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001117365,0.00004236005,0.000213178,0.0002952163,0.000009810126,0.0001583425,0.00007555644,0.0004978166,0.9861114,0.004532853,0.0002713284,0.007680421],"study_design_scores_gemma":[0.000004565101,0.000118568,0.0006946163,0.000008657837,0.000008271187,0.0001833501,0.00002921529,0.000730014,0.9909222,0.0004038451,0.006890735,0.00000588476],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.9023161,0.01053467,0.04761585,0.0007762587,0.0001380965,0.0002072317,0.0007382645,0.0003592142,0.03731428],"genre_scores_gemma":[0.970875,0.006012195,0.009101328,0.0002522514,0.00002260763,0.0001030757,0.0004757074,0.0000442641,0.01311356],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.003727073,"threshold_uncertainty_score":0.01246834,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00984621805941393,"score_gpt":0.2223153717647388,"score_spread":0.2124691537053248,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}