{"id":"W6986204380","doi":"","title":"The palladium catalyzed multicomponent synthesis of Münchnones : novel one-pot metal catalyzed routes to heterocycles and peptide-based molecules","year":2004,"lang":"en","type":"dissertation","venue":"eScholarship@McGill (McGill)","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Catalysis; Palladium; Molecule; Metal; Transition metal","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002449277,0.0004786955,0.0002645224,0.0003356356,0.0002205513,0.0004213732,0.0006487661,0.000261882,0.002852049],"category_scores_gemma":[0.0001608411,0.0002852031,0.0001998291,0.0004072042,0.0002964411,0.0006317786,0.0004552178,0.0007223447,0.001050214],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005197461,"about_ca_system_score_gemma":0.0003947425,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006622813,"about_ca_topic_score_gemma":0.001488054,"domain_scores_codex":[0.9998698,0.00002038947,0.000009320925,0.00003691169,0.00002246725,0.00004121104],"domain_scores_gemma":[0.9999642,0.000007566831,0.000007101698,0.000006530697,0.000004304236,0.0000102291],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001624361,0.000198707,0.0001153138,0.0003956622,0.00003399881,0.000405348,0.0003194954,0.002598171,0.921634,0.009116721,0.001115719,0.06390451],"study_design_scores_gemma":[0.00005949813,0.0004626651,0.0005309371,0.0000267617,0.00003082315,0.0004246038,0.00007574938,0.001999765,0.9734601,0.001052234,0.02184592,0.00003089166],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"methods","genre_scores_codex":[0.8493112,0.01356102,0.08175066,0.0005501113,0.0002940389,0.0004619209,0.0005896938,0.0005424788,0.052939],"genre_scores_gemma":[0.9076919,0.0119293,0.04412179,0.000195445,0.00003313971,0.0001355,0.0003115865,0.0001231131,0.03545827],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.002852049,"threshold_uncertainty_score":0.009541094,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01584174009660469,"score_gpt":0.2448643015848781,"score_spread":0.2290225614882734,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}