{"id":"W6987430786","doi":"","title":"Stereoelectronic effects of substituents at O-2 on glycosylation reactions","year":2010,"lang":"en","type":"article","venue":"NPARC","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Conformational isomerism; Density functional theory; Glycosylation; Lone pair; Hyperconjugation; Atom (system on chip); Ion","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002434997,0.0003374986,0.0002107902,0.0001502214,0.0003291216,0.0003391884,0.0003764356,0.0002202789,0.005992838],"category_scores_gemma":[0.0003772921,0.0001169142,0.0001315187,0.0001802339,0.0002023693,0.0002616095,0.000202457,0.0003599114,0.0002799704],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004072878,"about_ca_system_score_gemma":0.0002141763,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001861255,"about_ca_topic_score_gemma":0.002995385,"domain_scores_codex":[0.9999012,0.00001630647,0.000003660336,0.0000128075,0.00001870072,0.00004730496],"domain_scores_gemma":[0.9998993,0.00005272687,0.0000170293,0.000008636862,0.00001298559,0.0000093302],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.003335848,0.0004150377,0.008138499,0.001055195,0.00008948099,0.00163269,0.0005040069,0.06532624,0.8257421,0.03209719,0.003622081,0.05804167],"study_design_scores_gemma":[0.0002061637,0.001738706,0.008711075,0.00006419836,0.00009120913,0.0003691258,0.0003276744,0.1269917,0.8523563,0.004875494,0.004187975,0.00008031312],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916515,0.0003894628,0.001300613,0.0001227582,0.0000346687,0.000008584519,0.0001271905,0.00005159856,0.006313649],"genre_scores_gemma":[0.9986749,0.0002383402,0.0005066729,0.00003095795,0.000003348306,0.000006113955,0.00006901315,0.000008635422,0.0004619512],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005992838,"threshold_uncertainty_score":0.02004802,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005865619911953232,"score_gpt":0.2120970378498366,"score_spread":0.2062314179378834,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}