{"id":"W6990747474","doi":"","title":"Enantioselective Rhodium-catalyzed Hydroacylation of Alkenes and Ketones & Silver-catalyzed Hydroamination of Cyclopropenes","year":2012,"lang":"en","type":"dissertation","venue":"Library and Archives Canada (Government of Canada)","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hydroacylation; Hydroamination; Enantioselective synthesis; Intramolecular force; Aldehyde; Ketone; Olefin fiber","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.00004714844,0.0003580633,0.0006333236,0.00009343258,0.0001243197,0.00001500817,0.000208296,0.0001331045,0.000201371],"category_scores_gemma":[0.00005157067,0.0003693748,0.00006864651,0.0001760385,0.0001233823,0.0004897172,0.00008855332,0.0001601453,5.068485e-9],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001935549,"about_ca_system_score_gemma":0.001381329,"about_ca_topic_candidate":true,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.005013219,"about_ca_topic_score_gemma":0.02734953,"domain_scores_codex":[0.9968689,0.00007139263,0.0007633225,0.0003926025,0.001656713,0.0002470687],"domain_scores_gemma":[0.997816,0.0005874353,0.001106345,0.0003129089,0.00001034509,0.0001669953],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001375501,0.00009159294,0.01881449,0.002887751,0.0003342045,0.000002382978,0.0005291465,0.00006463338,0.9575729,0.00664169,0.00007874234,0.01160692],"study_design_scores_gemma":[0.0005565971,0.00001611049,0.07877322,0.0003491355,0.0002309434,0.000006417432,0.001694767,0.0004769584,0.9147701,0.0006932512,0.002062875,0.0003696649],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9186271,0.001414225,0.0001365995,0.0001353077,0.0002775662,0.0002381237,0.0006472792,0.00001422747,0.07850953],"genre_scores_gemma":[0.9782553,0.0004103179,0.001062544,0.00001692543,0.00008399165,0.00002217511,0.002113417,0.0000532387,0.01798209],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06052744,"threshold_uncertainty_score":0.9998758,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006294504099621305,"score_gpt":0.1916175459949731,"score_spread":0.1853230418953518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}