{"id":"W6990747474","doi":"","title":"Enantioselective Rhodium-catalyzed Hydroacylation of Alkenes and Ketones & Silver-catalyzed Hydroamination of Cyclopropenes","year":2012,"lang":"en","type":"dissertation","venue":"Library and Archives Canada (Government of Canada)","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hydroacylation; Hydroamination; Enantioselective synthesis; Intramolecular force; Aldehyde; Ketone; Olefin fiber","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001107541,0.0002815835,0.0001026938,0.0001421796,0.00009863247,0.0002125217,0.0001484285,0.00009095362,0.002154031],"category_scores_gemma":[0.00007569023,0.0000990894,0.0001371377,0.0001081797,0.0001106635,0.0001817672,0.0001396514,0.0003847787,0.001176579],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002214504,"about_ca_system_score_gemma":0.0002958059,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006780525,"about_ca_topic_score_gemma":0.001335894,"domain_scores_codex":[0.9999466,0.00000440408,0.00000325011,0.00001170909,0.00001990657,0.00001410583],"domain_scores_gemma":[0.9999832,0.000002064379,0.000003907258,0.000001990016,0.00000483518,0.000003885272],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004469991,0.00004326997,0.00008656235,0.00022282,0.000006170014,0.0001989747,0.0001252242,0.0002580417,0.9718528,0.001692749,0.0007755719,0.02469319],"study_design_scores_gemma":[0.000008153916,0.00005145536,0.0004134634,0.00001440854,0.00000577675,0.0001806487,0.0000309857,0.0002899377,0.9845398,0.00008001182,0.01438061,0.000004893747],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8214152,0.01249878,0.0259189,0.0006353072,0.0002163701,0.000184219,0.0005813356,0.0004185407,0.1381313],"genre_scores_gemma":[0.9153846,0.01235636,0.01121254,0.0001271409,0.00003554671,0.00005415612,0.0002962606,0.00005597682,0.06047743],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002154031,"threshold_uncertainty_score":0.007205904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006294504099621305,"score_gpt":0.1916175459949731,"score_spread":0.1853230418953518,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}