{"id":"W6992911114","doi":"","title":"The * Molecular Orbitals of Perfluoroalkanes as Studied by Inner-Shell Electron Energy Loss and Electron Transmission Spectroscopies","year":2010,"lang":"en","type":"article","venue":"York University Digital Library (York University)","topic":"Fullerene Chemistry and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada; National Science Foundation","keywords":"Delocalized electron; Spectral line; Atomic orbital; Molecular orbital; Ion; Oscillator strength; Excitation; Electron; Atomic electron transition","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001245235,0.0002261632,0.00008528434,0.0004542915,0.0002773767,0.0001905688,0.0002369549,0.000246652,0.00224861],"category_scores_gemma":[0.0002471659,0.0001000976,0.00009754187,0.0002616679,0.0002560621,0.0002900452,0.0001759791,0.0002138623,0.0001751517],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001884315,"about_ca_system_score_gemma":0.00008857608,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006529145,"about_ca_topic_score_gemma":0.0005632889,"domain_scores_codex":[0.999949,0.000005243491,0.000001129421,0.000005601103,0.00002192402,0.00001715771],"domain_scores_gemma":[0.9998982,0.00003822573,0.00002400586,0.000006162252,0.00002340303,0.00001009843],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003305759,0.00003613507,0.004161429,0.0001129008,0.00001718508,0.000273794,0.0002023098,0.003532484,0.9780526,0.003564107,0.0001590697,0.009557626],"study_design_scores_gemma":[0.00002899964,0.0003642892,0.04078663,0.0000342319,0.00002977309,0.0006445622,0.0003722265,0.03723757,0.915889,0.001804159,0.002766394,0.00004211118],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977188,0.0001516524,0.001081001,0.00001699498,0.000002218868,0.000001474104,0.00005139917,0.00001362494,0.0009627528],"genre_scores_gemma":[0.9987066,0.0001006443,0.0005782034,0.000008369151,0.000001107549,0.000003125293,0.0001103746,0.00000483968,0.0004867095],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00224861,"threshold_uncertainty_score":0.007522345,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.002370433278682692,"score_gpt":0.1583548976263783,"score_spread":0.1559844643476956,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}