{"id":"W6993132153","doi":"","title":"The novel sequential insertion of carbon monoxide and imines into palladium-carbon [sigma]-bonds : synthesis, mechanism and reactivity","year":2000,"lang":"en","type":"dissertation","venue":"eScholarship@McGill (McGill)","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Reactivity (psychology); Palladium; Carbon monoxide; Catalysis; Carboxylate","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000947439,0.0003474271,0.0001400225,0.0001670956,0.0001956851,0.0003302305,0.0005463079,0.0004105766,0.001697375],"category_scores_gemma":[0.0001238469,0.0002773693,0.0001430206,0.0001837409,0.0002039245,0.0004834282,0.0002710817,0.0004157012,0.0005899854],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002613273,"about_ca_system_score_gemma":0.0002283901,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005797205,"about_ca_topic_score_gemma":0.00123813,"domain_scores_codex":[0.9999132,0.00000784315,0.000006005626,0.00003286984,0.00001848362,0.00002165692],"domain_scores_gemma":[0.9999449,0.000007268251,0.00001546886,0.00001217712,0.000008584322,0.00001157098],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001245644,0.00005455283,0.0002235653,0.000269824,0.00001399798,0.0001997889,0.00007552812,0.0003440002,0.9857145,0.001878455,0.0002095472,0.01089158],"study_design_scores_gemma":[0.000008368615,0.0001968659,0.0002692663,0.000003108053,0.000007335418,0.0001726686,0.00001207967,0.0005891322,0.9934931,0.00006043375,0.005180496,0.000007098558],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9483399,0.005165454,0.02728408,0.0002685754,0.000120283,0.0001716345,0.000388815,0.0004735661,0.01778763],"genre_scores_gemma":[0.9660113,0.002465076,0.01323591,0.00005659293,0.00001787793,0.00008739576,0.0001663381,0.00003630752,0.01792325],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001697375,"threshold_uncertainty_score":0.005678236,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01239231782247749,"score_gpt":0.2259189496000598,"score_spread":0.2135266317775823,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}