{"id":"W7017921298","doi":"","title":"Caractérisation, mécanisme de formation et réactivité d'intermédiaires générés lors de l'oxydation de phénols par l'iode hypervalent","year":2023,"lang":"fr","type":"other","venue":"Archipelago (University of Quebec in Montreal)","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada","keywords":"Hypervalent molecule; Homogeneous; Iodine compounds","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002736436,0.0002958496,0.0001959753,0.000335775,0.0002541758,0.0004751158,0.0003474355,0.0003956723,0.003648477],"category_scores_gemma":[0.0003622042,0.0002237583,0.0002945637,0.0002611458,0.0003153837,0.0004157886,0.0001714041,0.0005216266,0.0005540248],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003580138,"about_ca_system_score_gemma":0.0002487945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002115456,"about_ca_topic_score_gemma":0.003003717,"domain_scores_codex":[0.9998192,0.0000184767,0.000006859807,0.00005173654,0.00005647184,0.00004718673],"domain_scores_gemma":[0.9997009,0.0001184547,0.00006838125,0.00002394595,0.00006132684,0.00002689293],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001993609,0.00001381337,0.002396709,0.0001804213,0.00001298385,0.0001245626,0.000201431,0.0002666199,0.9914607,0.0004575547,0.00007664884,0.004609137],"study_design_scores_gemma":[0.000003749488,0.0001245169,0.006618238,0.0000129916,0.00002073596,0.0001525521,0.0001629759,0.001268363,0.9879573,0.0001130718,0.003552347,0.00001318567],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9841681,0.002218306,0.01068905,0.0001009076,0.00002073405,0.00002919414,0.000382182,0.00008473844,0.002306761],"genre_scores_gemma":[0.9872831,0.001323533,0.006460416,0.00004137867,0.000006379307,0.00002999862,0.0003854986,0.00004276185,0.004427074],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003648477,"threshold_uncertainty_score":0.01220542,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0149996532739649,"score_gpt":0.2217103451325502,"score_spread":0.2067106918585853,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}